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差压热耦合反应精馏应用于乙酸甲酯水解研究
引用本文:李 军,王汝军,王丁丁,马占华,孙兰义.差压热耦合反应精馏应用于乙酸甲酯水解研究[J].中国石油大学学报(自然科学版),2014(1):155-160.
作者姓名:李 军  王汝军  王丁丁  马占华  孙兰义
作者单位:中国海洋大学化学化工学院;中国石油大学重质油国家重点实验室;
基金项目:国家自然科学基金(21276279);中央高校基本科研业务费专项(12CX04026A)
摘    要:结合差压热耦合和反应精馏工艺优势,提出形成差压热耦合反应的精馏工艺方法,将其应用于乙酸甲酯水解过程。在验证UNIQ-HOC模型对模拟该体系适用性的基础上,对影响该工艺的主要影响因素进行考察,得出优化后的主要操作参数,并对比差压热耦合精馏和常规流程的能耗。结果表明,差压热耦合反应精馏增加813.33 kW的功耗,减少7062.3 kW的热量,节能效果显著。

关 键 词:乙酸甲酯水解  差压热耦合  反应精馏  模拟优化  节能
收稿时间:2013/8/13 0:00:00

Simulation study of different pressure thermally coupled reactive distillation column for hydrolysis of methyl acetate
LI Jun,WANG Ru-jun,WANG Ding-ding,MA Zhan-hua and SUN Lan-yi.Simulation study of different pressure thermally coupled reactive distillation column for hydrolysis of methyl acetate[J].Journal of China University of Petroleum,2014(1):155-160.
Authors:LI Jun  WANG Ru-jun  WANG Ding-ding  MA Zhan-hua and SUN Lan-yi
Affiliation:LI Jun;WANG Ru-jun;WANG Ding-ding;MA Zhan-hua;SUN Lan-yi;Department of Chemistry and Chemical Engineering,Ocean University of China;State Key Laboratory of Heavy Oil Processing in China University of Petroleum;
Abstract:A different pressure thermally coupled reactive distillation column was proposed for the methyl acetate hydrolysis process by combining differential thermal coupled distillation with reactive distillation. It was verified that UNIQ-HOC model can be successfully applied to VLE prediction of this system. The main parameters affecting the process were investigated and the optimized operating parameters were obtained. The results show that the different pressure thermally coupled reactive distillation process can save about 89% of energy compared with the conventional process.
Keywords:methyl acetate hydrolysis  different pressure thermally coupled  reactive distillation  simulation and optimization  energy-saving
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