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氯离子浓度对含盐污水中有机污染物化学需氧量测定的影响研究
引用本文:路帅.氯离子浓度对含盐污水中有机污染物化学需氧量测定的影响研究[J].中国石油大学学报(自然科学版),2005,29(5).
作者姓名:路帅
作者单位:中国石油大学,化学化工学院,山东,东营,257061
摘    要:采用重铬酸钾法与高锰酸盐指数碱性法对水中化学需氧量(COD)进行了对比测定研究,考察了氯离子浓度对化学需氧量测定结果的影响。分析结果表明,对于低含氯水样(氯离子浓度小于1 000 mg/L),用重铬酸钾法测得的COD值(CODCr)和用高锰酸盐指数碱性法测得的COD值(CODOH)存在线性关系;而高含氯水样的CODCr和CODOH之间无线性相关性。高浓度氯离子对CODCr值的测定影响显著,其影响规律可以用二次多项式表示。

关 键 词:化学需氧量  有机污染物  高含氯污水  氯离子

Research on effects of concentration of chloride ion on chemical oxygen demand measurement of organic pollutant in saliferous wastewater
LU Shuai.Research on effects of concentration of chloride ion on chemical oxygen demand measurement of organic pollutant in saliferous wastewater[J].Journal of China University of Petroleum,2005,29(5).
Authors:LU Shuai
Abstract:The effects of ClO~-_4 on measurement of chemical oxygen demand(COD) of water were studied by comparison of potassium dichromate method and potassium permanganate method.The results show that the COD value(COD_(Cr)) by potassium dichromate method and the COD value(COD_(OH)) by potassium permanganate method have linear relationship for water sample with the low concentration of chloride ion(the concentration of chloride ion is less 1 000 mg per liter),while COD_(Cr) and COD_(OH) have no linear relationship for water sample with the high concentration of chloride ion.The high concentration of chloride ion has considerable effects on COD_(Cr) value which regularity could be expressed by second-degree polynomial.
Keywords:chemical oxygen demand  organic pollutant  wastewater with high concentration of chloride ion  chloride ion
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