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新型在线光谱测量方法在环境排放中的应用
引用本文:杨荟楠,王琴,杨正鹏,陈军,蔡小舒.新型在线光谱测量方法在环境排放中的应用[J].科技导报(北京),2015,33(6):79-85.
作者姓名:杨荟楠  王琴  杨正鹏  陈军  蔡小舒
作者单位:1. 上海理工大学能源与动力工程学院, 颗粒及两相流测量研究所, 上海200093;
2. 上海市多相流及传热传质重点实验室, 上海200093
基金项目:国家自然科学基金项目(51306123, 41375124);2013年高等学校博士点基金联合资助课题新教师类(20133120120008)
摘    要: 新型在线光谱测量方法, 如宽带腔增强吸收光谱及可调谐半导体激光吸收光谱技术, 由于其高灵敏度、原位实时以及较好的时间空间分辨率, 被广泛应用于环境排放监测。本文结合实际测量案例, 对腔增强吸收光谱技术在气态亚硝酸、气溶胶消光及可调谐激光在选择性催化还原脱硝中的液膜多参数测量中的应用研究做了总结回顾, 并认为两种测量技术的发展结合, 将为大气化学反应的核心活性物种测量、气溶胶消光参数的准确定量及非均相大气反应动力学测量提供有效的方法。

关 键 词:腔增强吸收光谱  大气亚硝酸  气溶胶消光  可调谐半导体激光吸收光谱  选择性催化还原系统  液膜  
收稿时间:2015-02-09

Novel in-situ spectroscopy methods for ambient emission studies
YANG Huinan,WANG Qin,YANG Zhengpeng,CHEN Jun,CAI Xiaoshu.Novel in-situ spectroscopy methods for ambient emission studies[J].Science & Technology Review,2015,33(6):79-85.
Authors:YANG Huinan  WANG Qin  YANG Zhengpeng  CHEN Jun  CAI Xiaoshu
Affiliation:1. Institute of Particle and Two-phase Flow Measurement; School of Energy and Power Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China;
2. Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering, Shanghai 200093, China
Abstract:Novel in-situ spectroscopy methods such as incoherent broad band cavity enhanced absorption spectroscopy (IBBCEAS) and tunable diode laser absorption spectroscopy (TDLAS) have been widely used for ambient emission studies due to their high sensitivity, real time, in-situ and high temporal and spatial resolutions. This work illustrates three real measurements of nitrous acid radical formation, aerosol extinction and multi-parameters of ammonia liquid film. It is conclusively shown that to develop and combine both methods will boost measurement of both atmospheric radical and aerosol extinction, as well as the studies of heterogeneous dynamical chemistry.
Keywords:cavity enhanced absorption spectroscopy  HONO  aerosol extinction  tunable diode laser absorption spectroscopy  selective catalytic reduction  liquid film  
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