| 两个新二茂铁酰基硫脲衍生物的合成与表征 |
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| 引用本文： | 杨怀霞,王利平,孟祥茹.两个新二茂铁酰基硫脲衍生物的合成与表征[J].河南科学,2007,25(2):208-210. |
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| 作者姓名： | 杨怀霞 王利平 孟祥茹 |
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| 作者单位： | 1. 郑州大学化学系,郑州,450052;河南中医学院,药学院,郑州,450008
2. 郑州大学化学系,郑州,450052 |
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| 基金项目： | 河南省教育厅自然科学基金 |
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| 摘 要： | 以二茂铁为原料,首先分别合成了1-二茂铁甲酸和1,1-’二茂铁二甲酸,然后通过酰化、缩合等一系列反应,得到了二个新的二茂铁酰基硫脲衍生物,并通过元素分析I、R1、HNMR等手段对其进行了表征,另外,初步试验证实二者具有良好的配位性能和植物调节活性.
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| 关 键 词： | 二茂铁 1-二茂铁甲酸 1 1-’二茂铁二甲酸 酰基硫脲 合成 |
| 文章编号： | 1004-3918(2007)02-0208-03 |
| 修稿时间： | 2006-11-20 |
Synthesis and Characterization of Two Novel Ferrocenoyl Thiourea Derivatives |
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| YANG Huai-xia,WANG Li-ping,MENG Xiang-ru.Synthesis and Characterization of Two Novel Ferrocenoyl Thiourea Derivatives[J].Henan Science,2007,25(2):208-210. |
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| Authors: | YANG Huai-xia WANG Li-ping MENG Xiang-ru |
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| Affiliation: | 1.Department of Chemistry, Zhengzhou University, Zhengzhou 450052,China; 2.Department of Chinese Medicine, Henan College of Traditional Chinese Medicine, Zhengzhou 450008, China |
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| Abstract: | 1-ferrocenecarboxylate and 1,1'-ferrocenedicarboxylate were synthesized with ferrocene as raw material, and then two novel ferrocenoyl thiourea derivativesⅠand Ⅱ were obtained through a series of acylation and condensation from them.Ⅰand Ⅱ were characterized by elemental analysis,IR and 1HNMR spectra.In addition,the primary experiments show that Ⅰand Ⅱ have better plant-growth regulatory activity and coordination properties. |
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| Keywords: | ferrocene 1-ferrocenecarboxylate 1 1-ferrocenedicarboxylate acetyl thiourea synthesis |
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