| 不同粒径聚丙烯腈基炭纳米微球制备的有效途径 |
| |
| 引用本文： | 张 琛,杨光智,史兴亚,马 明,靳 楠,陈 建.不同粒径聚丙烯腈基炭纳米微球制备的有效途径[J].山西科技,2014(2):27-30. |
| |
| 作者姓名： | 张 琛 杨光智 史兴亚 马 明 靳 楠 陈 建 |
| |
| 作者单位： | 上海理工大学材料科学与工程学院,上海200093 |
| |
| 基金项目： | 上海理工大学大学生创新创业训练计划. |
| |
| 摘 要： | 聚丙烯腈(PAN)基炭纳米微球是一种功能炭材料,在诸多领域有着广泛的应用前景。不同粒径PAN基炭纳米微球具有不同的结构与性能,其中合成不同粒径PAN纳米微球是制备炭纳米微球的瓶颈。通过权衡比较各种聚合物微球的合成方法和反应介质,认为以丙烯腈(AN)为原料,采用无皂乳液聚合法,在乙醇-水反应介质中可以合成不同粒径的PAN纳米微球。对合成的PAN纳米微球进行氧化和炭化,即可获得不同粒径的PAN基炭纳米微球。
|
| 关 键 词： | 聚丙烯腈 无皂乳液聚合法 乙醇-水介质 PAN纳米微球 氧化 炭化 PAN基炭纳米微球 |
The Effective Method for Preparing PAN-based Carbon Nanospheres with Different Diameters |
| |
| ZHANG Chen,YANG Guangzhi,SHI Xingya,MA Ming,JIN Nan,CHEN Jian.The Effective Method for Preparing PAN-based Carbon Nanospheres with Different Diameters[J].Shanxi Science and Technology,2014(2):27-30. |
| |
| Authors: | ZHANG Chen YANG Guangzhi SHI Xingya MA Ming JIN Nan CHEN Jian |
| |
| Affiliation: | ZHANG Chen, YANG Guangzhi, SHI Xingya, MA Ming, JIN Nan, CHEN Jian |
| |
| Abstract: | PAN-based carbon nanosphere, which is a kind of functional material, can be widely used in different fields. PAN-based carbon nanospheres with different diameters have different structures and performances, and the synthesis is the bottleneck to prepare PAN nanospheres with different diameters. Compared with lots of synthesizing methods and reaction mediums of polymeric microspheres, PAN nanospheres with different diameters can be synthesized in alcohol-water reaction medium by adopting soap-free emulsion polymerization. Followed by oxidation and carbonization, PAN-based carbon nanospheres with different diameters can be obtained. |
| |
| Keywords: | KEY WORDS： PAN soap-free emulsion polymerization alcohol-water reaction medium PAN nanospheres oxidation carbonization PAN-based carbonnanosphere |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
