| 含全氟壬烯基单体的合成与聚合 |
| |
| 引用本文： | 史鸿鑫,黄磊,陈立军,武宏科,项菊萍.含全氟壬烯基单体的合成与聚合[J].化工生产与技术,2011,18(3):1-3. |
| |
| 作者姓名： | 史鸿鑫 黄磊 陈立军 武宏科 项菊萍 |
| |
| 作者单位： | 浙江工业大学，绿色化学合成技术国家重点实验室培育基地，杭州310032 |
| |
| 摘 要： | 制备了1种含有全氟壬烯基的单体,与其他单体聚合得到含氟共聚物乳液.全氟壬烯(Ⅰ)和烯丙基(p-羟甲基苯基)醚(Ⅱ),在催化剂存在下得到含氟单体p-全氟壬烯基氧基苯酚烯丙基醚(Ⅲ)；以K2S2O8为引发剂,丙烯酸丁酯(BA)、甲基丙烯酸甲酯(MMA)和Ⅲ为共聚单体,采用乳液聚合的方法,制备了带蓝色荧光的含氟乳液.用傅立叶...
|
| 关 键 词： | 全氟壬烯 含氟单体 氟代共聚物 乳液聚合 接触角 |
| 收稿时间： | 2011-4-12 |
| 修稿时间： | |
Preparation and Polymization of a Monomer Containing Perfluorononyleneyl |
| |
| Shi Hongxin,Huang Lei,Chen Lijun,Wu Hongke,Xiang Juping.Preparation and Polymization of a Monomer Containing Perfluorononyleneyl[J].Chemical Production and Technology,2011,18(3):1-3. |
| |
| Authors: | Shi Hongxin Huang Lei Chen Lijun Wu Hongke Xiang Juping |
| |
| Affiliation: | Shi Hongxin,Huang Lei,Chen Lijun,Wu Hongke,Xiang Juping(State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology,Zhejiang University of Technology,Hangzhou 310032) |
| |
| Abstract: | A monomer containing perfluorononyleneyl was synthesized and co-polymerized with other monomers for a copolymer emulsion.p-Perfluorononenoxy-phenoxymethyl allyl ether(Ⅲ) was synthesized from perfluorononene(I) and allyl p-hydroxy-methylphenol ether(II) in the presence of a catalyst.The fluorinated-copolymer emulsion with blue-fluorescence was prepared by emulsion polymerization initiated by K2S2O8 from butyl acrylate(BA),methyl methacrylate(MMA) and Ⅲ.The monomer Ⅲ and Ⅲ-BA-MMA copolymers were characterized by FT-IR,1H-NMR,MS and/or contact angle measurement respectively.The yield of Ⅲ is 70.4% when n(I):n(II)=1:1,in the presence of pyridine and acetone as solvent at room temperature for 6 h.The hydrophobicity of the copolymer is improved when the fluorinated monomer Ⅲ is introduced.The water contact angle is 85.6° when 25% Ⅲ is used in the copolymer. |
| |
| Keywords: | perfluorononene fluorinated-monomer fluorinated copolymer emulsion polymerization contact angle |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《化工生产与技术》浏览原始摘要信息 |
|
点击此处可从《化工生产与技术》下载全文 |
|
