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Effects of nano-SiO2 on reinforcing and toughening polypropylene
Authors:WANG Dong-bo  FENG Yu-jie  TIAN Yan  HAN Li-wei
Affiliation:1. School of Municipal and Environmental Engineering,Harbin Institute of Technology,Harbin 150090,China;Environmental School,Guangxi University,Nanning 530004,China
2. School of Municipal and Environmental Engineering,Harbin Institute of Technology,Harbin 150090,China
3. Institute of Petrochemical of Heilongjiang Province,Harbin 150076,China
Abstract:SiO2 nano particle,through surface modification by silicane coupling agent KH-570,was successfully applied to make nano SiO2/PP composite material by the melt-out blending process with twin-screw extruder.Effects of nano SiO2 on the reinforcing and toughening of PP were studied by analyzing the material impact broken fracture,the crystal structure and the diameter of SiO2 nano particle using SEM,XRD and TEM,respectively.Results showed that the impact strength and the tensile strength of nano SiO2/PP composite material were improved apparently;the impact strength of PP was fracture was increased to 67%when the nano SiO2 content was4%;while the nano SiO2 particle upon surfsce treatment will impose obvious heterogeneous nucleation function over PP crystal.
Keywords:nano-silica particles  silicane coupling agent  toughening  polypropylene
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