| 烯酸加成酯化反应催化剂研究进展 |
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| 引用本文： | 俞峰萍,陶桂菊,谢同,金铭,何文军.烯酸加成酯化反应催化剂研究进展[J].工业催化,2019,27(6):16-25. |
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| 作者姓名： | 俞峰萍 陶桂菊 谢同 金铭 何文军 |
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| 作者单位： | 中国石油化工股份有限公司上海石油化工研究院,上海,201208;中国石油化工股份有限公司上海石油化工研究院,上海,201208;中国石油化工股份有限公司上海石油化工研究院,上海,201208;中国石油化工股份有限公司上海石油化工研究院,上海,201208;中国石油化工股份有限公司上海石油化工研究院,上海,201208 |
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| 基金项目： | 国家重点研发计划(2017YFB0702800) |
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| 摘 要： | 烯烃与羧酸在催化剂作用下进行加成反应生成羧酸酯,这一反应属于原子经济反应,越来越受到研究者的关注。综述21世纪以来烯烃与羧酸加成酯化反应催化剂的研究进展,包括磺酸类催化剂、离子交换树脂催化剂、杂多酸化合物催化剂、离子液体催化剂、沸石分子筛催化剂和过渡金属化合物催化剂等,对各类催化剂活性进行比较,并展望烯酸加成酯化反应催化剂的研究方向。
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| 关 键 词： | 催化剂工程 烯酸加成酯化 原子经济反应 离子交换树脂 |
Research progress on catalyst for esterification of carboxylic acid and olefin |
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| Yu Fengping,Tao Guiju,Xie Tong,Jin Min,He Wenjun.Research progress on catalyst for esterification of carboxylic acid and olefin[J].Industrial Catalysis,2019,27(6):16-25. |
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| Authors: | Yu Fengping Tao Guiju Xie Tong Jin Min He Wenjun |
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| Affiliation: | Shanghai Research Institute of Petrochemical Technology,SINOPEC,Shanghai 201208,China |
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| Abstract: | The esterification of carboxylic acid and olefin which is an atom economic reaction with 100% atom efficiency has attracted extensive attentions across academic and industrial communities.The research progress on catalysts for esterification of carboxylic acid and olefin was reviewed since 21st century including sulfonic acid based catalysts,ion exchange resin,heteropolyacid,ionic liquid,zeolite,transition metal compounds and so on.Catalytic performances of catalysts were compared and the research directions of catalysts used for esterification of carboxylic acid and olefin were also proposed. |
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| Keywords: | catalyst engineering esterification of carboxylic acid and olefin atom economic reaction ion exchange resin |
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