| 1,3-丙二醇合成工艺研究进展 |
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| 引用本文： | 周昱,姚洁,王公应.1,3-丙二醇合成工艺研究进展[J].天然气化工,2006,31(1):66-74. |
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| 作者姓名： | 周昱 姚洁 王公应 |
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| 作者单位： | 1. 中国科学院成都有机化学研究所,成都,610041;中国科学院研究生院,北京,100039
2. 中国科学院成都有机化学研究所,成都,610041 |
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| 摘 要： | 介绍了国内外1,3-PDO的合成工艺及其最新研究进展,较为详细的讨论了环氧乙烷羰基化法、丙烯醛水合法、微生物发酵法和醇醛缩合法的合成路线、工艺条件、催化剂等,并对其进行了综合比较,展望了今后的研究发展方向。
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| 关 键 词： | 1 3-丙二醇 丙烯醛 环氧乙烷 微生物发酵 醇醛缩合 |
| 文章编号： | 1001-9219（2006）01-66-08 |
| 收稿时间： | 2005-03-10 |
| 修稿时间： | 2005-03-10 |
Progress in the Synthesis of 1,3-propanediol |
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| ZHOU Yu,YAO Jie,WANG Gong-ying.Progress in the Synthesis of 1,3-propanediol[J].Natural Gas Chemical Industry,2006,31(1):66-74. |
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| Authors: | ZHOU Yu YAO Jie WANG Gong-ying |
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| Affiliation: | 1. Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041,China; 2. The Graduate School of the Chinese Academy of Sciences, Beijing 100039, China |
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| Abstract: | In this article, the routes of the synthesis of 1,3-propanediol are detailed. There are four synthesis routes, the hydration of acrolein followed by hydrogenation, hydroformylation of ethylene oxide, fermentation of glycerol and sacharides, and aldol condensation of formaldehyde and acetaldehyde followed by hydrogenation, which are discussed in detail and compared with each other in terms of reaction conditions including starting materials, catalysts, temperature, ressure, reaction time, and reactors. Recent developments are indicated. |
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| Keywords: | 1 3-propanedlol acrolein ethylene oxide fermentation aldol condensation |
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