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Effect of Ce-doping on catalysts derived from hydrotalcite-like precursors for COS hydrolysis
Authors:ZHAO Shunzheng  YI Honghong  TANG Xiaolong  NING Ping  WANG Hongyan  HE Dan
Affiliation:Faculty of Environmental Science and Engineering,Kunming University of Science and Technology
Abstract:In order to investigate the effect of Ce-doping on the catalysts derived from hydrotalcite-like precursors for carbonyl sulfide(COS) hydrolysis,a series of Zn-Ni-Al-Ce hydrotalcite-like compounds were prepared by co-precipitation method and the catalytic activity of their derived composite oxides were studied at 50 oC.The effect on the structural properties caused by Ce doping was studied by the X-ray diffractometer(XRD),scanning electron microscopy(SEM) and energy dispersive spectrometer(EDS).The catalytic activities results showed that addition of Ce enhanced the catalytic activities significantly,but excessive Ce-doping had a negative effect on COS hydrolysis.XRD,SEM and EDS results illustrated that,compared with the Ce-free sample,the particle size of oxide solids decreased and the degree of dispersion increased due to Ce doping.
Keywords:Ce-doping  hydrotalcite-like compounds  carbonyl sulfide  hydrolysis  rare earths
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