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打印涂层用聚氨酯胶粘剂的合成
引用本文:石红翠,贾金兰,毛祖秋,郭晓勇.打印涂层用聚氨酯胶粘剂的合成[J].涂料工业,2011,41(1).
作者姓名:石红翠  贾金兰  毛祖秋  郭晓勇
作者单位:山西省应用化学研究所,太原,030027
摘    要:以混合低聚物二醇、异佛尔酮二异氰酸酯、异佛尔酮二胺等为原料合成了固含最为45%的打印涂层用聚氨酯胶粘剂.讨论了不同种类的多元醇、二异氰酸酯及异氰酸酯与多元醇的物质的量比、不同小分子扩链剂对聚氨酯胶粘剂性能的影响,同时采用FT-IR、托力仪等测试仪器对聚氨酯胶粘剂进行结构表征、力学、硬度和耐水性测试.结果表明:选用聚酯PNA、聚氧化丙烯二醇PPG混合多元醇,n(-NCO):n(-OH)=4,m(1,4-丁二醇):m(新戊二醇)=6:2时,合成的聚氨酯胶粘剂膜硬度可达61,透明度良好,并有良好的抗粘连性和耐水性,满足打印涂层用聚氨酯胶粘剂的要求.

关 键 词:聚氨酯  打印涂层  聚氨酯树脂  胶粘剂

Development of Polyurethane Resin of Coating for Printing
Shi Hongcui,Jia Jinlan,Mao Zuqiu,Guo Xiaoyong.Development of Polyurethane Resin of Coating for Printing[J].Paint & Coatings Industry,2011,41(1).
Authors:Shi Hongcui  Jia Jinlan  Mao Zuqiu  Guo Xiaoyong
Affiliation:Shi Hongcui,Jia Jinlan,Mao Zuqiu,Guo Xiaoyong(Shanxi Insititute of Applied Chemistry,Taiyuan 030027,China)
Abstract:A 45% soid polyuretahe resin used for coatings on which printing is conducted was synthesised by diisocyanates with polyester glycol,polyether glycol,etc.Effect of different kinds of polyols and diisocyanates,mass ratio of diisocyanate and polyol,different kinds of chain extenders on polyurethane resin properties were discussed.The structure and mechanical property and water resistance polyurethane resin were characterized and tested by FT-IR and tensiometer,etc.The results showed that a process of polyuret...
Keywords:polyurethane  coating for printing  polyurethane resin  adhesive  
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