| 二聚5，6-二氧代-1，10-邻菲咯啉配合物的合成及结构分析 |
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| 引用本文： | 张宏坤,马丹雅,赵晶,朱传宝.二聚5，6-二氧代-1，10-邻菲咯啉配合物的合成及结构分析[J].合成材料老化与应用,2013,42(3):32-35. |
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| 作者姓名： | 张宏坤 马丹雅 赵晶 朱传宝 |
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| 作者单位： | 1. 黑龙江东方学院食品与环境工程学部,黑龙江哈尔滨,150086
2. 抚顺石化公司石油三厂,辽宁抚顺,113001 |
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| 摘 要： | 利用水热反应合成了聚5，6-二氧代-1，10-邻菲咯啉配合物晶体。同时利用X射线单晶衍射对标题化合物进行了表征。晶体数据：单斜晶系，空间群P2（1）／c，a=1．7365（4）nm，b=1．0961（2）nm，c=1．4424nm，β=111．75（3）°，V=2．5501（9）nm3，Dc=1．470mg／m3，Z=4，F（000）=1168，最终残差因子R1=0．0445，wR2=0．1053，对于全部数据R1=0．0915，wR2=0．1198。
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| 关 键 词： | 水热合成 配位聚合物 晶体结构 |
Synthesis and Structural Analysis of a Two-polymerization of 5,6-dioxo-1,10-Phenanthroline Monohydrate Coordination Polymer |
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| ZHANG Hong-kun
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MA Dan-ya
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ZHAO Jing
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ZHU Chuan-bao.Synthesis and Structural Analysis of a Two-polymerization of 5,6-dioxo-1,10-Phenanthroline Monohydrate Coordination Polymer[J].Synthetic Materials Aging and Application,2013,42(3):32-35. |
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| Authors: | ZHANG Hong-kun MA Dan-ya ZHAO Jing ZHU Chuan-bao |
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| Affiliation: | 1 Department of Food and Environmental Engineering,East University of Heilongjiang,Harbin 150086,Heilongjiang,China;2 No.3 Refinery of Fushun Petrochemical Company,Fushun 113001,Liaoning,China) |
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| Abstract: | a Two-Polymerization of 5,6-dioxo-1,10-Phenanthroline monohydrate Coordination Polymer has been synthesized through hydrothermal reaction and structurally characterized by single crystal X-ray diffraction method. In addition, the results of IR and 1H NMR analysis were presented. Crystal data ： tetragonal, space group P2（1）/c,a=1.7365（4）nm,b=1.0961（2）nm,c=1.4424nm,β=111.75（3）°,V=2.5501（9）nm3,Dc=1.470mg/m3,Z=4,F（000）=1168, final R indices I 〉2sigma（I） ] R1 = 0.0445,wR2 = 0. 1053,for all reflections R1= 0.0915, wR2 = 0. 1198. |
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| Keywords: | hydrothermal reaction coordination polymer crystal structure |
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