| 球碳C_(60)/C_(70)及其衍生物与环烷酸钴反应的光谱研究 |
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| 引用本文： | 于永良,薛美玲,梁玉华,孙靖宇,张玉冰.球碳C_(60)/C_(70)及其衍生物与环烷酸钴反应的光谱研究[J].应用化工,2003,32(3):6-8,15. |
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| 作者姓名： | 于永良 薛美玲 梁玉华 孙靖宇 张玉冰 |
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| 作者单位： | 1. 青岛科技大学,化学院,山东,青岛,266042
2. 天津大学,材料学院,天津,300072 |
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| 基金项目： | 国家自然科学基金资助项目(29674016) |
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| 摘 要： | 测定了球碳C60/C70及其衍生物C60Xn/C70Xn的加氢汽油溶液分别与环烷酸钴Co(naph)2]反应的紫外可见吸收光谱及C60Xn与Co(naph)2反应沉淀物的红外吸收光谱。结果表明:C60/C70及其衍生物均可与Co2+发生配位反应,形成π配体络合物,讨论了可能的反应机理。
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| 关 键 词： | 球碳及其衍生物 环烷酸钴 紫外可见吸收光谱 红外吸收光谱 |
| 文章编号： | 1671-3206(2003)03-0006-03 |
Study on spectrum of reactions of C60/C70 and it's derivatives with Co(naph)2 |
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| Abstract: | Fullerences(C60/C70) and it's derivatives(C60Xn/C70Xn) could react which Co(naph)2 respectively in hydrogenated gasoline solution, the reaction mixtures were analyzed by UV vis spectroscopy, and the IR spectroscopy of the reaction sediment was carred out simultaneously.The resuts showed that C60/C70 or it's derivatives were complexed with Co2+, and forming π complex compounds, the reaction mechanism was discussed. |
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| Keywords: | fullerences and it's derivatives Co(naph)_2 UV-vis IR |
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