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功能化活性炭固载离子液体催化剂
引用本文:崔露丹,马磊.功能化活性炭固载离子液体催化剂[J].浙江化工,2012,43(10):12-14,20.
作者姓名:崔露丹  马磊
作者单位:浙江工业大学工业催化研究所,浙江杭州,310032
摘    要:制备了活性炭固载溴化1-(2-胺乙基氢溴酸)-3-甲基咪唑翁盐离子液体催化剂,并用TG和XPS对催化剂进行了表征。将该催化剂首次用于Knoevenagel缩合反应,结果表明活性炭固载离子液体催化剂具有良好的催化活性和稳定性,同时克服了均相催化剂难以分离的不足。

关 键 词:离子液体  活性炭  固载  催化剂

Catalyst of Ionic Liquid Immobilized on the Functionalized Activated Carbon
CUI Lu-dan,MA Lei.Catalyst of Ionic Liquid Immobilized on the Functionalized Activated Carbon[J].Zhejiang Chemical Industry,2012,43(10):12-14,20.
Authors:CUI Lu-dan  MA Lei
Affiliation:(Industrial Catalysis Institute of Zhejiang University of Technology,Hangzhou,310032,China)
Abstract:Ionic liquid/activated carbons (AC) catalysts have been prepared by a chemical method that involves functionalization of AC with 1-(2-amine ethyl hydrogen)-3-methylimidazoliurn bromide ionic liquids. It was used in Knoevenagel condensation reaction for the first time.The immobilized IL was then characterized by X-ray photoelectron spectroscopy and thermogravimetric analysis (TGA) spectra. Ionic liquid/activated carbon (AC) catalyst showed good catalytic performance toward Knoevenagel condensation reaction,and overcome the inseparable shortage of the homogeneous catalyst.
Keywords:ionic liquid  activated carbon  immobilized  catalyst
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