| AlPO_4-5负载溴化铝催化酮的Baeyer-Villiger氧化反应 |
| |
| 引用本文： | 康瑞雪,张志芳,尹文梅,王爱娣,马国富.AlPO_4-5负载溴化铝催化酮的Baeyer-Villiger氧化反应[J].精细化工,2012(10):942-946,951. |
| |
| 作者姓名： | 康瑞雪 张志芳 尹文梅 王爱娣 马国富 |
| |
| 作者单位： | 西北师范大学化学化工学院生态环境相关高分子材料教育部重点实验室 |
| |
| 基金项目： | 国家自然科学基金(21164009,21174114);长江学者和创新团队发展计划(IRT1177)~~ |
| |
| 摘 要： | 以异丙醇铝为铝源,正磷酸为磷源,三乙胺作模板剂,采用水热反应合成了AlPO4-5分子筛。应用不同浓度氢溴酸对AlPO4-5分子筛进行化学剪裁,制备AlPO4-5-AlBr3催化剂。FESEM、XRD、N2吸附-脱附等表征结果表明,合成的AlPO4-5是规整的微孔六方棱柱,化学剪裁制备的担载型催化剂AlPO4-5-AlBr3依然保持规整的六方棱柱。催化氧化实验表明,质量分数30%双氧水作为氧化剂,在乙酸乙酯溶剂中,催化剂AlPO4-5-AlBr3对部分环酮具有较好的催化活性。
|
| 关 键 词： | 水热合成 化学剪裁 Baeyer-Villiger反应 催化技术 |
Baeyer-Villiger Oxidation of Ketons Catalyzed by AlPO4-5 Supported Aluminium Bromide |
| |
| KANG Rui-xue,ZHANG Zhi-fang,YIN Wen-mei,WANG Ai-di,MA Guo-fu.Baeyer-Villiger Oxidation of Ketons Catalyzed by AlPO4-5 Supported Aluminium Bromide[J].Fine Chemicals,2012(10):942-946,951. |
| |
| Authors: | KANG Rui-xue ZHANG Zhi-fang YIN Wen-mei WANG Ai-di MA Guo-fu |
| |
| Affiliation: | (Key Laboratory of Eco-environment-related Polymer Materials Ministry of Education,College of Chemistry and Chemical Engineering,Northwest Normal University,Lanzhou 730070,Gansu,China) |
| |
| Abstract: | AlPO4-5 molecular sieves were prepared by hydrothermal reaction using triethylamine as template,aluminum isopropoxide and orthophosphate as the source of aluminum and phosphorus.Via chemical tailoring method with different concentrations of hydrobromic acid,AlPO4-5-AlBr3 catalysts were obtained.Several techniques,such as high-resolution field-emission scanning electron microscopy(FESEM),X-ray diffraction(XRD) and N2 adsorption,were employed to investigate their morphology,structure as well as component.The characterization shows that AlPO4-5 was hexagonal crystal with microporous structure,after chemical tailoring,AlPO4-5-AlBr3 still maintained the structure.The catalytic test was performed using 30% H2O2(mass fraction) as oxidant and ethyl acetate as solvent.It is revealed that the catalyst had good performance for some ketons,and could be reused several times. |
| |
| Keywords: | hydrothermal synthesis chemical tailoring Baeyer-Villiger reaction catalytic technology |
| 本文献已被 CNKI 等数据库收录！ |
|
