Synthesis Routes and Characterization of High-Purity, Single-Phase Gallium Nitride Powders

Synthesis of high-purity, single-phase gallium nitride powder has been achieved in a hot-wall tube furnace via (i) the reaction of gallium with ammonia (NH₃) and (ii) the conversion of gallium oxide (Ga₂O₃). For complete reaction, the optimum temperatures, NH₃ flow rates, and boat positions relative to the NH₃ inlet were 975°C, 400 standard cubic centimeters per minute (sccm), and 50 cm, respectively, for the gallium-NH₃ reaction, and 1050°C, 500 sccm, and 50 cm, respectively, for the Ga₂O₃ conversion. Polyhedra of various shapes were obtained from both processes; some rod-shaped crystals also were observed in the material derived from Ga₂O₃.