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醇+1,2-二氯乙烷、醇+环己酮二元体系热导率的测定和推算
引用本文:尉小明,雷群芳,刘刚强,林瑞森.醇+1,2-二氯乙烷、醇+环己酮二元体系热导率的测定和推算[J].化工学报,2001,52(12):1078-1082.
作者姓名:尉小明  雷群芳  刘刚强  林瑞森
作者单位:浙江大学化学系
摘    要:采用瞬态热丝法液体热导率测量装置测定 10种醇 (甲醇、乙醇、正丙醇、异丙醇、正丁醇、异丁醇、仲丁醇、叔丁醇、正戊醇和异戊醇 )分别与 1,2 -二氯乙烷、环己酮组成的 2 0个二元体系在常压、 30℃和不同组成时的热导率 ,测量误差± 0 .7% .用文献中 5种热导率方程对所测液体的热导率做了推算 ,将计算值与实测结果做了比较 ,并进行了讨论

关 键 词:热导率  瞬态热丝法  二元体系  液体混合物  实验测定  推算  热力学性质    1  2-二氯乙烷  环已酮
文章编号:0438-1157(2001)12-1078-05
修稿时间:2000年2月28日

MEASUREMENT AND CALCULATION ON THERMAL CONDUCTIVITY FOR BINARY SYSTEMS OF ALCOHOLS WITH 1,2-DICHLOROETHANE AND WITH CYCLOHEXANONE
WEI Xiaoming,LEI Qunfang,LIU Gangqiang,LIN Ruisen.MEASUREMENT AND CALCULATION ON THERMAL CONDUCTIVITY FOR BINARY SYSTEMS OF ALCOHOLS WITH 1,2-DICHLOROETHANE AND WITH CYCLOHEXANONE[J].Journal of Chemical Industry and Engineering(China),2001,52(12):1078-1082.
Authors:WEI Xiaoming  LEI Qunfang  LIU Gangqiang  LIN Ruisen
Abstract:Thermal conductivites at 30℃ and atmospheric pressure for 20 binary mixtures of 10 kinds of alcohols, methanol, ethanol, n -propanol, iso -propanol, n -butanol, iso -butanol, sec -butanol, tert -butanol, n -pentanol and iso -pentanol,with 1,2-dichloroethane and with cyclohexanone, respectively, were measured by transient hot wire method with the uncertainty of less than ±0.7%.Five different thermal conductivity predictive equations from literatures were used to calculate the thermal conductivities of these liquid mixtures investigated.The calculated values are compared with the experimental data from this work and the results were discussed.
Keywords:thermal conductivity  transient hot wire method  binary system  liquid mixture  experimental determination  calculation
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