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Iridoid glucosides in Griselinia, Aralidium and Toricellia
Authors:Søren Rosendal Jensen  Bent Juhl Nielsen
Affiliation:Department of Organic Chemistry, The Technical University of Denmark, 2800 Lyngby, Denmark
Abstract:From three of five investigated species of Griselinia a new iridoid glucoside, griselinoside, was isolated. It was found to be present also in foliage of Aralidium pinnatifidum and Toricellia angulata, accompanied in the former by aralidioside another novel iridoid glucoside. The structures and absolute configurations of the two iridoids were elucidated by NMR spectroscopy and chemical conversions. From G. littoralis and T. angulata the glucosides magnolioside and syringoside respectively were isolated. 13C NMR spectra are given for thirteen iridoid derivatives.
Keywords:Cornales  iridoid glucosides  griselinoside  aralidioside  coumarin glucoside  magnolioside
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