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基于反应成膜技术的水基丙烯酸酯乳液包衣控释肥料的研制(英文)
引用本文:申亚珍,赵聪,周健民,杜昌文.基于反应成膜技术的水基丙烯酸酯乳液包衣控释肥料的研制(英文)[J].中国化学工程学报,2015,23(1):309-314.
作者姓名:申亚珍  赵聪  周健民  杜昌文
作者单位:State Key Laboratory of Soil and Sustainable Agriculture, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, China
基金项目:Supported by the National 12th Five-Year Science and Technology Supporting Program(2011BAD11B01);the Research & Development Projects Cooperation Project of Chinese Academy of Sciences(YDJDBNJ-2012-023)
摘    要:Waterborne acrylic emulsions modified with organic siloxanes and aziridine crosslinker were synthesized and applied as coating of controlled release fertilizer. The free films were characterized and the nutrient release pro-files of the coated fertilizers were determined. The results show that methyl silicone oil and methylsilanolate so-dium could not improve water resistance performance and glass transition temperature Tg of coatings, while the firmness is enhanced. Aziridine crosslinker improves the water resistance performance, firmness and Tg. Incorpo-ration of methyl silicone oil and aziridine crosslinker gives an excellent aqueous acrylic emulsion for coated con-trol ed release fertilizer, with the 30-day cumulative nutrient release reduced to 16%and an estimated nutrient release duration over 190 days. Therefore, this waterborne coating is promising to meet the requirements for controlled release of nutrient and environmental protection.

关 键 词:Controlled  release  fertilizer  Acrylic  emulsion  Siloxane  Crosslinker  Reacted  layer  technology  
收稿时间:2013-03-01

Application of waterborne acrylic emulsions in coated controlled release fertilizer using reacted layer technology
Yazhen Shen;Cong Zhao;Jianmin Zhou;Changwen Du.Application of waterborne acrylic emulsions in coated controlled release fertilizer using reacted layer technology[J].Chinese Journal of Chemical Engineering,2015,23(1):309-314.
Authors:Yazhen Shen;Cong Zhao;Jianmin Zhou;Changwen Du
Affiliation:State Key Laboratory of Soil and Sustainable Agriculture, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, China
Abstract:Waterborne acrylic emulsions modified with organic siloxanes and aziridine crosslinker were synthesized and applied as coating of controlled release fertilizer. The free films were characterized and the nutrient release pro-files of the coated fertilizers were determined. The results show that methyl silicone oil and methylsilanolate so-dium could not improve water resistance performance and glass transition temperature Tg of coatings, while the firmness is enhanced. Aziridine crosslinker improves the water resistance performance, firmness and Tg. Incorpo-ration of methyl silicone oil and aziridine crosslinker gives an excellent aqueous acrylic emulsion for coated con-trol ed release fertilizer, with the 30-day cumulative nutrient release reduced to 16%and an estimated nutrient release duration over 190 days. Therefore, this waterborne coating is promising to meet the requirements for controlled release of nutrient and environmental protection.
Keywords:Control ed release fertilizer  Acrylic emulsion  Siloxane  Crosslinker  Reacted layer technology
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