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膨润土与碱反应的初步研究
引用本文:曹吉林,章永洁,李琳,邸立辉,张丽静,宋宝俊.膨润土与碱反应的初步研究[J].过程工程学报,2002,2(3):204-208.
作者姓名:曹吉林  章永洁  李琳  邸立辉  张丽静  宋宝俊
作者单位:1. 河北工业大学化工学院,天津,300130
2. 河北工业大学现代教学中心,天津,300130
摘    要:将经焙烧与不经焙烧的膨润土与氢氧化钠反应,考察了反应时间和氢氧化钠浓度对膨润土中硅铝浸出的影响. 测定了不同焙烧温度和焙烧时间条件下膨润土与碳酸钠固相反应生成物中可溶性硅铝的含量,并通过热重分析实验对此固相反应进行了研究. 结果表明:接近碳酸钠熔点时固相反应最剧烈,膨润土中63.85%的SiO2和96.78%的Al2O3可被浸出转变为水溶性物质.

关 键 词:膨润土  固相反应  热重分析  碳酸钠  氢氧化钠
文章编号:1009-606X(2002)03-0204-05
修稿时间:2001年10月17

Preliminary Study on the Reaction of Bentonite and Alkalis
CAO Ji-lin,ZHANG Yong-jie,LI Lin,DI Li-hui,ZHANG Li-jing,SONG Bao-jun.Preliminary Study on the Reaction of Bentonite and Alkalis[J].Chinese Journal of Process Engineering,2002,2(3):204-208.
Authors:CAO Ji-lin  ZHANG Yong-jie  LI Lin  DI Li-hui  ZHANG Li-jing  SONG Bao-jun
Affiliation:CAO Ji-lin1,ZHANG Yong-jie1,LI Lin2,DI Li-hui1,ZHANG Li-jing1,SONG Bao-jun1
Abstract:Experiment on reaction of bentonite and calcined bentonite with sodium hydroxide was carried out, and the effects of reaction time and concentration of sodium hydroxide on the leached silicon and aluminium from bentonite were investigated. The dissoluble silicon and aluminium in the product from solid reaction of bentonite and sodium carbonate at different calcining temperatures and calcining time were determined. Chemical analysis and thermogravimetry show that the solid reaction of bentonite and sodium carbonate proceeds intensely at the temperatures close to the melting point of sodium carbonate, and 63.85%(w) of SiO2 and 96.78%(w) of Al2O3 in bentonite can be converted to water-soluble compounds.
Keywords:bentonite  solid reaction  thermogravimetry  sodium carbonate  sodium hydroxide  
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