| 基于磷杂菲基团阻燃环氧树脂的研究进展 |
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| 引用本文： | 姚忠樱,邱勇,杨喜生,赵震,钱立军.基于磷杂菲基团阻燃环氧树脂的研究进展[J].中国塑料,2020,34(5):77-86. |
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| 作者姓名： | 姚忠樱 邱勇 杨喜生 赵震 钱立军 |
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| 作者单位： | 1. 北京工商大学材料与机械工程学院，北京 1000482. 塑料卫生与安全质量评价技术北京市重点实验室，北京 1000483. 山东兄弟科技股份有限公司，山东 潍坊 262737 |
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| 基金项目： | 国家自然科学基金(51973006) |
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| 摘 要： | 综述了近些年来基于9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物(DOPO)及其衍生物为主的添加型阻燃剂和反应型阻燃固化剂(包括DOPO中P-H键与C=N、C=O、C=C之间的反应)应用于环氧树脂材料中的研究概况,总结了每种体系的性能特点与阻燃机理,并对未来基于磷杂菲基团阻燃环氧树脂的发展进行了展望。
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| 关 键 词： | 磷杂菲基团 环氧树脂 添加型阻燃剂 反应型阻燃固化剂 |
| 收稿时间： | 2019-12-04 |
Research Progress in DOPO⁃based Flame⁃retardant Epoxy Resins |
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| Zhongying YAO,Yong QIU,Xisheng YANG,Zhen ZHAO,Lijun QIAN.Research Progress in DOPO⁃based Flame⁃retardant Epoxy Resins[J].China Plastics,2020,34(5):77-86. |
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| Authors: | Zhongying YAO Yong QIU Xisheng YANG Zhen ZHAO Lijun QIAN |
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| Affiliation: | 1. School of Materials and Mechanical Engineering，Beijing Technology and Business University，Beijing 100048，China2. Beijing Key Laboratory of Quality Evaluation Technology for Hygiene and Safety of Plastics，Beijing 100048，China3. ShanDong Brother Sci. &Tech. Co. , Ltd, Shandong Weifang 262737, China |
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| Abstract: | This paper reviewed the recent research progress in the addition-type flame retardants based on 9,10-dihydro-9-oxa-10-phosphenanthrene-10-oxide(DOPO)for epoxy resins as well as the reactive flame-retardant curing agents involved in the reaction between the P-H bond and the C=N,C=O and C=C bonds.The performance characteristics and relevant mechanisms of each flame-retardant system are summarized.Moreover,the future trend in development of DOPO-based flame-retardant epoxy resins was prospected. |
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| Keywords: | 9 10-dihydro-9-oxa-10-phosphenanthrene-10-oxide groups epoxy resin additive flame retardant reactive flame-retardant curing agent |
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