| 甲醇对噻吩在HZSM-5分子筛上转化反应的影响 |
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| 引用本文： | 罗立文,李虎,于慧征,夏道宏.甲醇对噻吩在HZSM-5分子筛上转化反应的影响[J].工业催化,2005,13(10):11-14. |
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| 作者姓名： | 罗立文 李虎 于慧征 夏道宏 |
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| 作者单位： | 中国石油大学(华东)化学化工学院,重质油国家重点实验室，山东 东营257061 |
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| 基金项目： | 重质油国家重点实验室开放课题（No.E030407-2）;教育部优秀青年教师资助计划项目（No.20011863） |
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| 摘 要： | 在固定床微型反应器中，以HZSM-5（硅铝物质的量比为25）分子筛为催化剂，探讨了甲醇对噻吩催化脱硫转化反应的影响。实验表明，反应温度在350 ℃以上时，噻吩转化率达到51％以上；甲醇与溶剂苯的合适体积比为1∶2；负载于HZSM-5的氧化镧对噻吩的催化转化有较大的促进作用；负载氧化镧质量分数为1.0%时，噻吩的转化率和硫化氢的产率分别达到51.3％和18.1％，与母体HZSM-5分子筛催化剂相比，噻吩的转化率和硫化氢的产率分别提高了36.0％和11.9％；空速以14 h-1为宜。
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| 关 键 词： | ZSM-5分子筛 甲醇 噻吩 催化脱硫 |
| 文章编号： | 1008-1143(2005)10-0011-04 |
| 收稿时间： | 2005-01-20 |
| 修稿时间： | 2005-08-31 |
Influence of methanol on conversion of thiophene over HZSM-5 zeolites |
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| LUO Li-wen, LI Hu, YU Hui-zheng, XIA Dao-hong , Dongying ,China.Influence of methanol on conversion of thiophene over HZSM-5 zeolites[J].Industrial Catalysis,2005,13(10):11-14. |
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| Authors: | LUO Li-wen LI Hu YU Hui-zheng XIA Dao-hong Dongying China |
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| Affiliation: | College of Chemistry and Chemical Engineering, State Key Laboratory of Heavy Oil Processing,;China University of Petroleum (East China), Dongying 257061,China |
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| Abstract: | Influence of methanol on catalytic desulfurization of thiophene over HZSM-5 (silica-to-alumina molar ratio = 25) was studied in fixed bed micro-reactor. The experimental results showed that thiophene conversion of over 51% was obtained at the temperature of over 350 ℃. The appropriate volumetric ratio between methanol and benzene was 1∶2. Satisfactory results (thiophene conversion of 51.3% and hydrogen sulfide yield of 18.1%) were attained over HZSM-5 zeolite modified by 1.0% La (mass fraction), with enhancement in thiophene conversion and hydrogen sulfide yield by 36.0％ and 11.9％, respectively, compared with purely HZSM-5 zeolite. Weight hourly space velocity（WHSV） of 14 h-1 was preferable. |
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| Keywords: | ZSM-5 zeolite methanol thiophene catalytic desulfurization |
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