| 5-硝基苯并三唑-1-乙酸镝与1,10-邻菲啰啉配合物的合成和性质研究 |
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| 引用本文： | 任宁,张大海,柴兴泉,董春华,张建军.5-硝基苯并三唑-1-乙酸镝与1,10-邻菲啰啉配合物的合成和性质研究[J].化学试剂,2012(5):395-397. |
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| 作者姓名： | 任宁 张大海 柴兴泉 董春华 张建军 |
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| 作者单位： | 邯郸学院化学系;河北师范大学实验中心 |
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| 基金项目： | 国家自然科学基金资助项目(21073053);河北省科技支撑项目资助(09215135) |
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| 摘 要： | 采用溶液合成法,合成了标题化合物,通过元素分析、摩尔电导率、紫外光谱、红外光谱和热分析法确定配合物的组成为Dy(L)3phen.1.5H2O(HL=5-硝基苯并三唑-1-乙酸;phen=1,10-邻菲啰啉)。荧光光谱表明:镝配合物的荧光强度较强,说明配体5-硝基苯并三唑-1-乙酸和1,10-邻菲啰啉是很好的敏化剂。
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| 关 键 词： | 稀土 配合物 5-硝基苯并三唑-1-乙酸 荧光 |
Synthesis and properties of dysprosium complex with 2-(5-nitro-1H-benzo[d]triazol-1-yl)acetic acid ligand and 1,10-phenanthroline |
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| REN Ning,ZHANG Da-hai,CHAI Xing-quan,DONG Chun-hua,ZHANG Jian-jun.Synthesis and properties of dysprosium complex with 2-(5-nitro-1H-benzo[d]triazol-1-yl)acetic acid ligand and 1,10-phenanthroline[J].Chemical Reagents,2012(5):395-397. |
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| Authors: | REN Ning ZHANG Da-hai CHAI Xing-quan DONG Chun-hua ZHANG Jian-jun |
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| Affiliation: | 1.Department of Chemistry,Handan College,Handan 056005,China;2.Experimental Center,Hebei Normal University,Shijiazhuang 050016,China) |
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| Abstract: | Dysprosium complex based on 2-(5-nitro-1H-benzod]triazol-1-yl) acetic acid and 1,10-phenanthroline was synthesized by the solution method.The composition of the title complex was confirmed to be Dy(L)3phen·1.5H2O(HL=2-(5-nitro-1H-benzod]triazol-1-yl) acetic acid;phen=1,10-phenanthroline) by means of elemental analysis,molar conductivity,UV,IR and thermal analysis.The fluorescence spectra showed that the title complex exhibited strong fluorescence,indicating that the 2-(5-nitro-1H-benzod]triazol-1-yl) acetic acid and 1,10-phenanthroline ligand was the good sensitizer. |
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| Keywords: | rare earth complex 2-(5-nitro-1H-benzo[d]triazol-1-yl) acetic acid fluorescence |
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