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Bi过量和Mn掺杂的钛酸铋钠基无铅压电陶瓷
引用本文:杜鹃,王矜奉,赵明磊,陈洪存,梁兴华,盖志刚,苏文斌,臧国忠.Bi过量和Mn掺杂的钛酸铋钠基无铅压电陶瓷[J].电子元件与材料,2006,25(4):1-3.
作者姓名:杜鹃  王矜奉  赵明磊  陈洪存  梁兴华  盖志刚  苏文斌  臧国忠
作者单位:山东大学物理与微电子学院,山东,济南,250100
基金项目:中国科学院资助项目;山东省自然科学基金
摘    要:采用传统电子陶瓷制备工艺制备(1–y)(Na0.5Bi0.5)TiO3-yBa(ZrxTi1–x)O3无铅压电陶瓷,获得了d33高达185pC/N的0.94(Na0.5Bi0.5)TiO3-0.06Ba(Zr0.055Ti0.945)O3压电陶瓷。对Bi的挥发进行了补偿,添加过量Bi2O3(摩尔分数z=0.08)的钛酸铋钠基压电陶瓷,d33高达218pC/N。研究了Mn掺杂对钛酸铋钠基陶瓷压电、介电性能和损耗的影响,获得了高性能的无铅压电陶瓷,其中d33为214pC/N,kt为0.44,k33为0.52。

关 键 词:无机非金属材料  无铅压电陶瓷  掺杂  压电常数  机电耦合系数
文章编号:1001-2028(2006)04-0001-03
收稿时间:2005-11-07
修稿时间:2005年11月7日

Mn-doped Lead-free Piezoelectric (Na, Bi)TiO3 Based Ceramics Compensated with Extra Bi
DU Juan,WANG Jin-feng,ZHANG Ming-lei,CHEN Hong-cun,LIANG Xing-hua,GAI Zhi-gang,SU Wen-bin,ZANG Guo-zhong.Mn-doped Lead-free Piezoelectric (Na, Bi)TiO3 Based Ceramics Compensated with Extra Bi[J].Electronic Components & Materials,2006,25(4):1-3.
Authors:DU Juan  WANG Jin-feng  ZHANG Ming-lei  CHEN Hong-cun  LIANG Xing-hua  GAI Zhi-gang  SU Wen-bin  ZANG Guo-zhong
Affiliation:School of Physics and Mieroelectronies, Shandong University, Jinan 250100, China
Abstract:Lead-free piezoelectric ceramics(1-y)(Na0.5Bi0.5)TiO3-yBa(ZrxTi1-x)O3 were fabricated using the conventional ceramics technique.The composition 0.94(Na0.5Bi0.5)TiO3-0.06Ba(Zr0.55Ti0.945)O3 is obtained with d33 as high as 185 pC/N.By means of compensating the volatilization of Bi2O3,(Na,Bi)TiO3 based ceramics doped with extra 0.08%(mole fraction)Bi2O3 can be obtained with d33 as high as 195 pC/N.The effects of doping Mn on the piezoelectric,dielectric constant and dielectric loss are investigated,and the acquired(Na,Bi)TiO3 based lead-free piezoelectric ceramics have optimal properties:d33=214 pC/N,kt = 0.44,k33 = 0.52.
Keywords:inorganic non-metallic materials  lead-free piezoelectric ceramics  doping  piezoelectric constant  electromeehanieal coupling factors
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