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品系对天然橡胶臭氧老化性能的影响
引用本文:陈琅,廖建和,黄桂春,李维国,陈永平,王兵兵,杜日鹏,周娟.品系对天然橡胶臭氧老化性能的影响[J].热带作物学报,2016,37(3):602-608.
作者姓名:陈琅  廖建和  黄桂春  李维国  陈永平  王兵兵  杜日鹏  周娟
作者单位:1. 海南大学材料与化工学院,海南海口,570100;2. 海南大学应用科技学院,海南儋州,571737;3. 海南天然橡胶集团金隆加工分公司,海南白沙,572818;4. 中国热带农业科学院橡胶研究所,海南儋州,571737
基金项目:国家自然科学基金(No. 002003040)。
摘    要:对比分析5个栽培条件相近主栽品系的天然橡胶的结构与性能差异,发现RRIM600性能最好,拉伸强度达30.21 MPa,耐臭氧老化性能最优。通过分析非胶组分,结合ATR-FTIR与热重分析仪器初步探究其耐臭氧老化差异的原因:RRIM600橡胶树生产的橡胶非胶组分杂质与灰分含量低,蛋白质含量适中,P0、PRI较高,分子链结构规整,橡胶中含有较多的胺基抑制臭氧化反应,使得分子链受到保护,综合表现出较好的耐臭氧性能。

关 键 词:品系  天然橡胶  臭氧老化  结构

The Ozone Aging Properties of Natural Rubber of Different Rubber Strains
CHEN Lang,LIAO Jianhe,HUANG Guichun,LI Weiguo,CHEN Yongping,WANG Bingbing,DU Ripeng and ZHOU Juan.The Ozone Aging Properties of Natural Rubber of Different Rubber Strains[J].Chinese Journal of Tropical Crops,2016,37(3):602-608.
Authors:CHEN Lang  LIAO Jianhe  HUANG Guichun  LI Weiguo  CHEN Yongping  WANG Bingbing  DU Ripeng and ZHOU Juan
Affiliation:Materials and Chemical Engineering, Hainan University;College of Applied Science and Technology, Hainan University,;Jinlong Processing Branch, Hainan Natural Rubber Group;Institute of Rubber Research, Chinese Academy of Tropical Agricultural Sciences;Materials and Chemical Engineering, Hainan University;Materials and Chemical Engineering, Hainan University;College of Applied Science and Technology;Jinlong Processing Branch, Hainan Natural Rubber Group
Abstract:The structure and properties of natural rubber of five strains were studied. It was found The strain RRIM600 had better performance to resistant ozone aging and the tensile strength was 30.21 Mpa. Through the rubber component analysis, combining with FTIR- ATR and TG analysis instrument, we preliminarily probed into its superior ozone aging resistance: In non-rubber constituent, the content of impurities and the content of ash were the lowest; Protein content was moderate; P0, PRI was the highest; The molecular chain structure was neat. It contained more amino group to inhibit the reaction with ozone. These made the molecular chains be protected
Keywords:Rubber strain  Natural rubber  Ozone aging properties  Structure
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