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Fe(phen)_3~(2 )光度法研究Fenton试剂体系中·OH生成率的影响因素
作者单位:南京大学环境工程系 南京210093 (罗刚),哈尔滨工业大学市政环境工程学院 哈尔滨150090 (黄君礼),佳木斯水文水资源勘测局 佳木斯154002 (于克浩),南京大学环境工程系 南京210093(张全兴)
摘    要:提高Fenton试剂在废水处理工艺中的效率 ,关键在于提高体系中·OH的生成率与利用率。本文采用间接测定·OH的方法 ,对Fenton试剂体系中·OH的表观生成率进行测定。并详细考查了催化剂Fe2 的浓度、H2 O2 的投加量、pH值、反应时间及反应温度等因素对体系中·OH的表观生成率的影响。为提高Fenton试剂处理废水的效率提供了有用的参数

关 键 词:Fenton试剂  ·OH的表观生成率  废水处理  影响因素

Study on the Influence Factors of the Apparent Productivity of Hydroxyl Radicals in Fenton's Reagent System by Fe(phen)_3~(2 )Spectrophotometry
Authors:Luo Gang  Huang Junli  Yu Kehao  Zhang Quanxing
Affiliation:Luo Gang 1 Huang Junli 2 Yu Kehao 3 Zhang Quanxing 1
Abstract:The key to enhance the efficiency of Fenton's reagent in wastewater treatment is to enhance the productivity and utilization ratio of hydroxyl radicals in the system.In this paper,the apparent productivity of hydroxyl radicals in Fenton's reagent system was determined by the method of indirect determination.The leading factors influencing the apparent productivity of hydroxyl radicals in the system such as the concentration of catalyst ferrous iron(Fe 2 ,the amounts of H 2O 2,pH,reaction time and reaction temperature were tested in detail.The useful parameters for Fentionis reagent treating wastewater were offered.
Keywords:Fenton's reagent  The apparent productivity of hydroxyl radicals  Wastewater treatment  Influence factors
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