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可见光响应的壳-核结构Ag/AgCl光催化剂性能
引用本文:周建伟.可见光响应的壳-核结构Ag/AgCl光催化剂性能[J].工业催化,2009,17(10):69-72.
作者姓名:周建伟
作者单位:新乡学院能源与燃料研究所,河南 新乡 453003
基金项目:河南省高校科技创新人才支持计划资助,新乡市科技发展计划项目 
摘    要:利用光化学还原法制备了Ag/AgCl壳-核结构的复合纳米粒子,以亚甲基蓝为模型降解物,研究了其可见光催化性能。结果表明,壳-核结构的Ag/AgCl纳米材料具有表面等离子效应,提高了其对可见光吸收和光催化活性。在可见光照射下,亚甲基蓝溶液浓度为10 mg·L-1,催化剂用量10 mg·L-1,光照60 min,亚甲基蓝降解率达95%,COD去除率为92%。

关 键 词:催化化学  Ag/AgCl纳米粒子  可见光  光催化降解  亚甲基蓝  表面等离子体  

Photocatalytic properties of visible light responsive shell-core type Ag/AgCl catalyst
ZHOU Jianwei.Photocatalytic properties of visible light responsive shell-core type Ag/AgCl catalyst[J].Industrial Catalysis,2009,17(10):69-72.
Authors:ZHOU Jianwei
Affiliation:Institute of Energy and Fuels, Xinxiang University, Xinxiang 453003, Henan,China
Abstract:Using AgCl nanoparticles as the crystal seeds and in the presence of trisodium citrate, Ag/ AgCl core-shell composite nanoparticles were synthesized by photochemical reduction method and their photocatalytic properties were investigated using methylene blue degradation as the model reaction. The results showed that the Ag/AgCl nanoparticles exhibited surface plasma resonance effect, effectively enhancing absorption of visible light and the photocatalytic activity, methylene blue degradation rate of 95% and COD removal rate of 92% were obtained under the following condition: catalyst dosage 10 mg·L-1, methylene blue concentration 10 mg ·L-1 , visible light irradiation for 60 min.
Keywords:catalytic chemistry  Ag/AgC  nanoparticle  visible light  photocatalytic degradation  methylene blue  surface plasma
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