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Evaluation of biosynthesized nickel oxide nanoparticles from Clerodendrum phlomidis: A promising photocatalyst for methylene blue and acid blue dyes degradation
Affiliation:1. Department of Chemistry, Saveetha School of Engineering, Saveetha Institute of Medical and Technical Sciences, Saveetha University, Chennai, 602 105, Tamil Nadu, India;2. Department of Physics, Saveetha School of Engineering, Saveetha Institute of Medical and Technical Sciences, Saveetha University, Chennai, 602 105, Tamil Nadu, India;3. Department of Chemistry, SRM Institute of Science and Technology (SRMIST), Kattankulathur, 603 203, Kancheepuram (DT), Tamil Nadu, India;1. School of Materials Science and Engineering, Zhengzhou University, Zhengzhou, 450001, China;2. School of Material Science and Engineering, Henan University of Technology, Zhengzhou, 450001, China;1. Key Laboratory of Marine New Materials and Related Technology, Key Laboratory of Marine Materials and Protective Technologies of Zhejiang Province, Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences, No.1219 Zhongguan West Road, Ningbo, 315201, China;2. Key Laboratory of Pressure System and Safety, Ministry of Education, School of Mechanical and Power Engineering, East China University of Science and Technology, No.130 Meilong Road, Shanghai, 200237, China;3. AECC Commercial Aircraft Engine Co., LTD, China;4. School of Mechanical Engineering, Anhui Polytechnic University, Wuhu, 241000, China;1. Department of Chemistry, SRM Institute of Science and Technology, Kattankulathur, Tamil Nadu 603203, India;2. Interdisciplinary Institute of Indian System of Medicine, SRM IST, Kattankulathur, Tamil Nadu 603203, India;1. Department of Chemical, Metallurgical and Materials Engineering, Tshwane University of Technology, P.M.B. X680, Pretoria, South Africa;2. Surface Engineering Research Laboratory, Tshwane University of Technology, P.M.B. X680, Pretoria, South Africa;3. Department of Electrical Engineering, Tshwane University of Technology, P.M.B. X680, Pretoria, South Africa;1. School of Physics and Materials Science, Nanchang University, Nanchang, 330000, PR China;2. Ganjiang Innovation Academy, Chinese Academy of Sciences, Ganzhou, 341000, PR China;3. Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, PR China
Abstract:In the present investigation, nickel oxide nanoparticles (NiO) were biosynthesized utilizing an extract of Clerodendrum phlomidis leaves. Their size, phase study, and shape were investigated using a variety of research methods. In addition, we assessed the photocatalytic effects of NiO nanoparticles on the degradation of methylene blue (MB) and acid blue (AB) dyes. Throughout the research process, we found that these nanoparticles had extraordinary potential for photocatalysis when exposed to UV light. This is a 100% environmentally friendly method that makes no use of any harmful or poisonous solvents. High-resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, and ultraviolet–visible spectroscopy (UV–Vis) were used to analyze the biosynthesized NiO nanoparticles. The catalytic activity of the newly synthesized nanoparticles was evaluated by seeing how well they degraded dyes called methylene (MB) and acid blue (AB). Following the first-order reaction, kinetics was the photocatalytic effectiveness against the methylene blue (MB) and acid blue (AB) dyes, both of which exhibited a maximum degradation efficiency of 92% and 63%. Because of this, the biosynthesized NiO nanoparticles synthesized utilizing the extract of Clerodendrum phlomidis leaves have the potential to be used in photocatalytic applications.
Keywords:Biosynthesis  Nickel oxide  Photocatalytic degradation
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