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含呋咱衍生物富燃料推进剂的能量性能
引用本文:张君启,张炜,朱慧,张兴高.含呋咱衍生物富燃料推进剂的能量性能[J].火炸药学报,2006,29(4):36-40.
作者姓名:张君启  张炜  朱慧  张兴高
作者单位:国防科学技术大学航天与材料工程学院,湖南,长沙,410073
摘    要:采用最小自由能法,研究了含呋咱衍生物的Al/Mg/HTPB/AP富燃料推进剂的能量性能,结果表明,随着呋咱衍生物含量的增加,富燃料推进剂比冲明显增加,其中含质量分数为25%的DAAzF(4,4'-二氨基-3,3'-偶氮呋咱)的富燃料推进剂比冲可达7 522.9 N·s·kg-1,比相同质量含量下含CL-20富燃料推进剂比冲高260N·s·kg-1.含呋咱衍生物富燃料推进剂气相平均相对分子质量((-M)g)约为29,补燃室火焰温度(Tc)约为2 200K,且二者随着呋咱衍生物含量增加而略有增加.

关 键 词:物理化学  富燃料推进剂  能量性能  呋咱  比冲
文章编号:1007-7812(2006)04-0036-05
收稿时间:03 3 2006 12:00AM
修稿时间:04 26 2006 12:00AM

The Energy Properties of Fuel-rich Propellants Comprising Furazan Derivatives
ZHANG Jun-qi,ZHANG Wei,ZHU Hui,ZHANG Xing-gao.The Energy Properties of Fuel-rich Propellants Comprising Furazan Derivatives[J].Chinese Journal of Explosives & Propellants,2006,29(4):36-40.
Authors:ZHANG Jun-qi  ZHANG Wei  ZHU Hui  ZHANG Xing-gao
Abstract:Furazan is a kind of novel high energy material and has a good future application in propellants and explosives. This work studies the energy properties of Al/Mg/HTPB/AP fuel-rich propellants comprising furazan derivatives. The results reveal that the specific impulse (Is) of propellant comprising DAAzF is the largest with propellant comprising CL-20 at the same mass fraction(w). The mean relative molecular mass(Mg) of propellants comprising furazans is about 29, the flame temperature in after-burning chamber(Tc) is about 2200K, and the values of (-M)g and Tc increase with increasing the mass fraction of furazans.
Keywords:physical chemistry  fuel-rich propellant  energy properties  furazan  specific impulse
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