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含铟锌浸渣中铟浸出动力学研究
引用本文:张帆,魏昶,邓志敢,李存兄,李兴彬,李旻廷.含铟锌浸渣中铟浸出动力学研究[J].有色金属工程,2016,6(1).
作者姓名:张帆  魏昶  邓志敢  李存兄  李兴彬  李旻廷
作者单位:昆明理工大学,昆明理工大学,昆明理工大学,昆明理工大学,昆明理工大学,昆明理工大学
基金项目:国家重点基础研究发展计划(973计划);国家自然科学基金项目(面上项目,重点项目,重大项目)
摘    要:本文以含铟锌浸渣为对象,研究其在硫酸溶液中的浸出动力学。考察了搅拌转速、硫酸浓度、三价铁浓度、反应温度和矿物粒度等实验条件对铟浸出速率的影响。结果表明:其浸出过程可用没有固体产物层生成的“未反应核收缩模型”描述;浸出反应的表观活化能为 J/mol;对硫酸浓度与三价铁浓度的表观反应级数分别为0.985与-0.096;含铟锌浸渣的浸出过程受化学反应控制。

关 键 词:  动力学模型  浸出  含铟锌浸渣
收稿时间:2015/7/30 0:00:00
修稿时间:8/2/2015 12:00:00 AM

A kinetic study of indium leaching from indium-bearing zinc residue in sulfuric acid solution
ZHANG Fan,WEI Change,DENG Zhi-gan,LI Cun-xiong,LI Xing-bin and LI Min-ting.A kinetic study of indium leaching from indium-bearing zinc residue in sulfuric acid solution[J].Nonferrous Metals Engineering,2016,6(1).
Authors:ZHANG Fan  WEI Change  DENG Zhi-gan  LI Cun-xiong  LI Xing-bin and LI Min-ting
Affiliation:Kunming University of Science and Technology,Kunming University of Science and Technology,Kunming University of Science and Technology,Kunming University of Science and Technology,Kunming University of Science and Technology,Kunming University of Science and Technology
Abstract:This paper presented a study for leaching kinetic indium from indium-bearing zinc residue in H2SO4 solution. The shrinking core model was applied to the results of experiments investigating the effects of stirrer speed, H2SO4 concentration, ferric ion concentration, leaching temperature and particle size on indium dissolution rate. The activation energy for the leaching process was found to be J/mol. The reaction order with respect to sulfuric acid and ferric ion concentrations were approximately 0.985 and -0.096, respectively. The dissolution of indium from indium-bearing zinc residue in H2SO4 solution was found to be controlled by reaction-controlled process.
Keywords:Indium  Kinetic-model  Leaching  Indium-bearing zinc residue
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