| 水杨醛缩胺类双席夫碱过渡金属配合物的合成与表征 |
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| 引用本文： | 李翠勤,孟祥荣,张鹏,景常荣,刘长环,朱秀雨.水杨醛缩胺类双席夫碱过渡金属配合物的合成与表征[J].化学与生物工程,2011,28(7):55-57. |
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| 作者姓名： | 李翠勤 孟祥荣 张鹏 景常荣 刘长环 朱秀雨 |
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| 作者单位： | 1. 东北石油大学化学化工学院,黑龙江大庆,163318
2. 大庆石化公司化工一厂,黑龙江大庆,163714 |
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| 基金项目： | 黑龙江省教育厅资助项目 |
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| 摘 要： | 以水杨醛与乙二胺为原料,通过席夫碱反应合成一类水杨醛缩胺类双席夫碱,并进一步与铜、锌、镍3种金属离子络合得到3种过渡金属配合物；采用元素分析、红外光谱和紫外光谱对席夫碱及其金属配合物的结构进行表征.结果表明,合成的水杨醛缩乙二胺配体分子结构与理论结构相符,且分别与铜、锌、镍离子络合形成了稳定的过渡金属配合物.
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| 关 键 词： | 水杨醛 席夫碱反应 金属配合物 |
Synthesis and Characterization of Transition Metal Complexes with Salicylaldehyde-Amine Dis-Schiff Base |
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| LI Cui-qin,MENG Xiang-rong,ZHANG Peng,JING Chang-rong,LIU Chang-huan,ZHU Xiu-yu.Synthesis and Characterization of Transition Metal Complexes with Salicylaldehyde-Amine Dis-Schiff Base[J].Chemistry & Bioengineering,2011,28(7):55-57. |
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| Authors: | LI Cui-qin MENG Xiang-rong ZHANG Peng JING Chang-rong LIU Chang-huan ZHU Xiu-yu |
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| Affiliation: | 1(1.College of Chemistry & Chemical Engineering,Northeast Petroleum University,Daqing 163318,China;2.No.1 Chemical Plant,Daqing Petrochemical Company,Daqing 163714,China) |
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| Abstract: | The ligand of salicylaldehyde-amine dis-Schiff base was synthesized by Schiff base reaction using ethylenediamine and salicylaldehyde as raw materials.Three kinds of transition metal complexes were prepared by complexing Cu,Zn and Ni with the Schiff base.The structure of products was characterized by elemental analysis,IR and UV-Vis.The results of characterization proved the structure of salicylaldehyde-amine ligand conformed with the target construction,and stable transition metal complexes were formed by it with Cu,Zn and Ni,respectively. |
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| Keywords: | salicylaldehyde Schiff base reaction metal complex |
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