Fluorescent chemosensor based on the conjugated polymer incorporating 2,2′‐bipyridyl moiety for transition metal ions |
| |
Authors: | Qian Miao Xiaobo Huang Yaqian Cheng Yan Liu LiLi Zong Yixiang Cheng |
| |
Affiliation: | 1. College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325027, China;2. School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China |
| |
Abstract: | A fluorescent conjugated polymer was synthesized by the polymerization of 1,4‐dibromo‐2,3‐bisbutoxynaphthalene ( M‐2 ) with 5,5′‐divinyl‐2,2′‐bipyridine ( M‐3 ) via Heck reaction. The conjugated polymer shows strong blue–green fluorescence because of the extended π‐electronic structure between the repeating unit 2,3‐bisbutoxynaphthyl group and the conjugated linker 2,2′‐bipyridyl (bpy = 2,2′‐bipyridine) moiety via vinylene bridge. The responsive properties of the conjugated polymer on transition metal ions were investigated by fluorescent and UV–vis spectra. The results show that Cu2+ and Ni2+ can form nonradiative metal‐to‐ligand charge‐transfer complexes with the polymer, whereas, Zn2+ and Cd2+ do not produce the pronounced differences from the polymer fluorescence and UV–vis spectra. The fluorescent quenching can probably be attributed to the intramolecular photoinduced electron transfer (PET) or photoinduced charge transfer (PCT). The results can also suggest that 2,2′‐bipyridyl moiety in the main chain backbone of the conjugated polymer can act as the recognition site of a special fluorescent chemosensor for sensitive detection of transition metal ions. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 |
| |
Keywords: | conjugated polymer fluorescent chemosensor 2 2′ ‐bipyridine Heck reaction |
|
|