| 二硝基重氮酚重氮化反应机理再探 |
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| 引用本文： | 谢斌.二硝基重氮酚重氮化反应机理再探[J].爆破器材,1995(6):1-5. |
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| 作者姓名： | 谢斌 |
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| 作者单位： | 湖南１６９厂 |
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| 摘 要： | 文中依据杂化理论分析了亚硝酸的结构特点，主要以分子结构理论为基础，从理论上指出在ＤＤＮＰ重氮化反应中，可能是氯化亚硝酰作为重氮反应的亲电试剂，其进攻发生在氨基的氮上，从而推测了获得ＤＤＮＰ的反应历程。
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| 关 键 词： | 二硝基重氮酚 合成 重氮化反应 亲电试剂 |
Restudy of the Mechanism of Diazotization of Diazodinitrophenol |
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| Xie BingNo.,Factory.Restudy of the Mechanism of Diazotization of Diazodinitrophenol[J].Explosive Materials,1995(6):1-5. |
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| Authors: | Xie BingNo Factory |
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| Affiliation: | Hunan 417124 |
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| Abstract: | The structural charaCteristic of nitrous acid is analyzed based on the hybrid theory and particularly on the basis of the molecular structure theory, it is presumed that the nitrosyl chloride may be a electrophilic reagent in diazotization of diazodinitrophenol which attacks the. amidonitrogen to promote the reaction for formation of diazodinitrophenol. |
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| Keywords: | diazodinitrophenol chemical synthesis diazotization reaction electrophilic reagent |
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