| 14种二茂铁亚胺类化合物的制备和紫外－可见光谱研究 |
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| 引用本文： | 石进超,郑晓晖,阿米娜.14种二茂铁亚胺类化合物的制备和紫外－可见光谱研究[J].西北大学学报,1995(1). |
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| 作者姓名： | 石进超 郑晓晖 阿米娜 |
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| 作者单位： | 西北大学化学系，西安医科大学药学系，喀什师范学院 |
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| 摘 要： | 报道了９种取代苯胺基亚胺二茂铁类化合物Ｒ－Ｎ＝ＣＨＦｃ［Ｒ为＿６Ｈ＿（５＿ａ＿ｘ＿ａ（ｘ＝Ｈ，４ Ｂｒ，４ＳＯ＿３Ｈ，４ＯＣＨ＿３，２，４（ＮＯ＿２）＿２）和２，４（ＮＯ＿２）＿２Ｃ＿６Ｈ＿４ＮＨ］及５种取代苯亚甲基亚胺二茂铁类化合物ｘ＿ｎ（２ＯＨ）Ｃ＿６Ｈ＿（４－ｎ）。ＣＨ＝Ｎ—Ｆｃ［ｘ＝Ｈ，５－Ｂｒ，５－ＮＯ＿２，５ＮＯ：５Ｂｒ３，５（ＮＯ＿２）＿２］的制备，测定了它们的紫外光谱，指定了谱带的归属，并对谱带的位移从理论上予以解释。
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| 关 键 词： | 甲酰基二茂铁 氨基二茂铁 缩合 紫外分光光度法 |
The Preparation and UV/Vis Spectra of Fourteen of the Iminoferrocene Compounds |
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| Shi Jinchao, Zheng Xiaohui,A Mi'na.The Preparation and UV/Vis Spectra of Fourteen of the Iminoferrocene Compounds[J].Journal of Northwest University(Natural Science Edition),1995(1). |
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| Authors: | Shi Jinchao Zheng Xiaohui A Mi'na |
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| Abstract: | Nine substituted phenyl iminomethyl ferrocenes R-N=CHFc(R:-C_6H_(5-n),x_n(X=H,4- Br,4-OH,4-SO_3H,4-COOH,4-OCH_3,2-CH_3,2,4-(NO_2)2),2,3-(NO_2)_2,C_6H_4NH-]and five subst;tuted phenyl methyliminoferrocenes X_n(2-OH)C_6H_(4-n)CH=N-FcX=H,5-Br,5-NO_2,3-NO_2-5-Br,3,5-(NO_2)_2]are prepared and characterized by UV/Vis spectra.The spectral bands are assigned and the shift of the bands explained theoretically. |
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| Keywords: | formylferrocene aminoferrocene condensation UV spectrophotometry |
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