Low-temperature heat capacities of crystalline Ho(Gly)_3Cl_3·3H_2O from 78 to 348 K |
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Authors: | ZHANG Jingnan WANG Hui TAN Zhicheng LIU Beiping SHI Quan TONG Bo |
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Affiliation: | Thermochemistry Laboratory Dalian Institute of Chemical Physics Chinese Academy of Sciences Shanghai Research Institute of Petrochemical Technology SINOPEC China Ionic Liquids Laboratory Department of Chemistry Hunan University of Arts and Science |
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Abstract: | Heat capacities of the rare-earth complex with glycine Ho(Gly)3Cl3·3H2O] were measured with a high-precision automatic adiabatic calorimeter over the temperature range from 78 to 348 K.In the experimental temperature range,the heat capacities increased in a smooth and continuous manner and no phase transition or thermal anomaly occurred.Therefore,the sample was stable in the above temperature range.The values of experimental heat capacities were fitted to a polynomial equation with least square method and ... |
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Keywords: | rare-earth complex low-temperature heat capacities thermodynamic functions |
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