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端氨基蔗渣纤维素对水中重金属离子微污染吸附的研究进展
引用本文:夏璐,张博涵,龚铸,邓啟敏.端氨基蔗渣纤维素对水中重金属离子微污染吸附的研究进展[J].食品安全质量检测技术,2014,5(10):3035-3041.
作者姓名:夏璐  张博涵  龚铸  邓啟敏
作者单位:广西民族大学化学化工学院; 广西林产化学与工程自治区重点实验室,广西民族大学化学化工学院,广西民族大学化学化工学院,广西民族大学化学化工学院
基金项目:国家自然科学基金项目(41461092, 41061044)、广西自然科学基金项目(2012GXNSFAA053017)
摘    要:在重金属污染日益严重的今天,重金属污染的治理已经越来越受到广泛的关注。纤维素分子含有大量的羟基,但天然纤维素吸附能力并不好,通过化学改性后可成为性能良好的吸附剂。纤维素无污染、易生物降解、且来源广泛价格低廉,对其研究已成为该领域的热点,并已被广泛应用于重金属污染治理领域。超支化聚合物大分子作为一类制备工艺并不繁琐且容易得到树状高分子聚合物,其最大特点就是准球形的分子结构及末端官能团的可控性,其研究愈加受到关注。本文在文献综述的基础上,提出合成一种含有端氨基超支化合物结构的蔗渣改性重金属吸附剂的可行性技术设想。

关 键 词:重金属离子    吸附    蔗渣纤维素    端氨基超支化    改性
收稿时间:2014/9/16 0:00:00
修稿时间:2014/9/29 0:00:00

Research progress on preparation of amino-terminated hyperbranched polymer graft bagasse cellulose and on its adorption properties of heavy metal ions
XIA Lu,ZHANG Bo-Han,GONG Zhu and DENG Qi-Min.Research progress on preparation of amino-terminated hyperbranched polymer graft bagasse cellulose and on its adorption properties of heavy metal ions[J].Food Safety and Quality Detection Technology,2014,5(10):3035-3041.
Authors:XIA Lu  ZHANG Bo-Han  GONG Zhu and DENG Qi-Min
Affiliation:School of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Key Laboratory of Development,School of Chemistry and Chemical Engineering, Guangxi University for Nationalities,School of Chemistry and Chemical Engineering, Guangxi University for Nationalities and School of Chemistry and Chemical Engineering, Guangxi University for Nationalities
Abstract:On account of the pollution problems caused by heavy metals becoming more and more serious, the technology of heavy metal treatment has received more and more attentions in nowadays. As an effective adsorbent, cellulosic materials were largely developed on industrial purpose being abundant in hydroxyl groups, but the adsorption ability of natural cellulose was still unsatisfactory for its large numbers of internal and interactive hydrogen bonds. Therefore, some modifications should be taken on the surface of cellulose molecular. Because of its unique properties of non-polluting, easily degradable, facile available, and low-cost, modified cellulose as heavy metal absorbent has already been intensively applied in separating and extracting of heavy metal ions from aqueous solution in this decade. Known as a type of dendritic polymers, the preparation processes of hyperbranched polymers are simple, and its torispherical molecular structure and terminal functional groups are controllable. Hence, the technology and development of these hyperbranched polymers are becoming more and more popular to current researchers. This paper reviewed the progress and proposed a feasible idea on synthesis of a containing amino terminated hyperbranched polymer structure of bagasse modification of heavy metal adsorbent.
Keywords:heavy metal ions  adsorption  bagasse cellulose  amino-termination  hyperbranch
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