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Fabrication and modification of polyvinylchloride based heterogeneous cation exchange membranes by simultaneously using Fe-Ni oxide nanoparticles and Ag nanolayer: Physico-chemical and antibacterial characteristics
Authors:Akbar Zendehnam  Mina Arabzadegan  Sayed Mohsen Hosseini  Nasrin Robatmili  Sayed Siavash Madaeni
Affiliation:1. Thin Film Laboratory, Department of Physic, Faculty of Science, Arak University, Arak, 38156-8-8349, Iran
2. Department of Chemical Engineering, Faculty of Engineering, Arak University, Arak, 38156-8-8349, Iran
3. Membrane Research Centre, Department of Chemical Engineering, Faculty of Engineering, Razi University, Kermanshah, 67149, Iran
Abstract:Polyvinylchloride-blend-styrene butadiene rubber based nanocomposite cation exchange membranes were prepared by solution casting technique. Iron-oxide nanoparticles and Ag-nanolayer were simultaneously utilized as filler and surface modifier in membrane fabrication. The effects of Ag-nanolayer film thickness on membrane physicochemical and antibacterial characteristics of nanocomposite PVC-blend-SBR/Iron-oxide nanoparticles were studied. SEM images showed membrane roughness decreasing by Ag nanolayer thickness increasing. Membrane charge density and selectivity declined by Ag nanolayer coating up to 5 nm in membranes and then showed increasing trend by more nanolayer thickness. Ionic flux also showed increasing trend. Membranes showed good ability in E-Coli removal. 20 nm Ag-nanolayer coated membrane showed better performance compared to others.
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