| CuO／SiO2和CuO—ZnO／SiO2催化剂的热分析性质 |
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| 引用本文： | 周亚明,刘金香.CuO／SiO2和CuO—ZnO／SiO2催化剂的热分析性质[J].复旦学报(自然科学版),1998,37(3):330-334. |
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| 作者姓名： | 周亚明 刘金香 |
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| 作者单位： | [1]复旦大学 [2]中国科学院大连化学物理研究所 |
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| 摘 要： | 用差热分析（ＴＧ／ＤＴＡ）技术研究了ＣｕＯ／ＳｉＯ２和ＣｕＯ－ＺｎＯ／ＳｉＯ２催化剂于Ｈ２气下的还原行为和在Ｏ２气下的氧化行为及对其催化性能的影响。结果表明，ＺｎＯ的加入有利于催化剂的热稳定性，并对ＣｕＯ的还原有促进作用；在有氧化气氛存在时，ＺｎＯ的加入不利于保持Ｃｕ＾０的还原态。
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| 关 键 词： | 催化剂 甲醇 甲酸甲酯 热分析 |
Thermal Analysis of the CuO/SiO_2 and CuO-ZnO/SiO_2 Catalysts |
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| Zhou Yaming, Xu Hualong, Sheng Wei, Xiang Yifei, Liu Jinxiang.Thermal Analysis of the CuO/SiO_2 and CuO-ZnO/SiO_2 Catalysts[J].Journal of Fudan University(Natural Science),1998,37(3):330-334. |
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| Authors: | Zhou Yaming Xu Hualong Sheng Wei Xiang Yifei Liu Jinxiang |
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| Abstract: | The reduction behavior under H2 atmosphere and oxidation behavior under O2 at mosphere and their influence to its catalytic character of CuO/SiO2, and CuO-ZnO/SiO2 cata lysts have been investigated by means of DTA and TG. The results show that the thermal stability titled catalysts is raised by ZnO. The existence of ZnO accelerate the rate of reduc tion of Cuo and is no good for Cuo. |
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| Keywords: | CuO/SiO_2 catalyst TG/DTA methanol methyl formate |
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