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Preparation of Porous Ceramics with Calcium Metaphosphate Fiber Skeleton for Biomedical Use
Authors:ihiro Kasuga      Tatsuya Inoue†  Kenji Tsuji†  Yoshio Ota†  §  Yoshihiro Abe  
Affiliation:Department of Materials Science and Engineering, Nagoya Institute of Technology, Nagoya 466, Japan
Yabashi Industries Company Ltd., Ogaki, Gifu 503-22, Japan
Abstract:High-strength calcium metaphosphate fibers for biomedical applications are extracted from crystallized products of calcium ultraphosphate glasses by aqueous leaching. In the present work, new types of porous ceramics with a skeleton composed of the crystalline fibers are prepared by heating the fibrous products extracted. The fibers in the ceramic are interlinked to each other by glassy phases formed during the heating. This porous material has a large porosity of >60%. The surface of the skeleton can be successfully converted into new calcium phosphate phases such as apatite by heating the porous material treated with a molten salt mixture of CaCl2-Ca(NO3)2.
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