The Solution kinetics of zirconium in liquid steel

Zirconium cylinders were immersed into liquid steel and their mass-transfer rates were measured under static and dynamic conditions. The cylinders were suspended from a load cell, and the apparent weight of the dissolving specimen as well as temperatures at various locations in the samples were measured continuously during immersion and recorded with a data acquisition System. From the weight measurements, the mass-transfer rate was deduced. In the assimilation of zirconium in liquid steel two periods were identified, i.e. the steel shell period and the free dissolution period. Immediately upon immersion the steel shell period Starts and when this period ends the free dissolution period commences. During the steel shell period, a shell of frozen steel wraps around the cylinder following its initial immersion. When zirconium cylinders were immersed into liquid steel, a reaction was detected at the steel shell/zirconium interface. This reaction took place almost immediately after immersion. The intermetallic Compounds Fe₂Zr and FeZr₂ were identified as reaction products. The experimentally measured mass transfer rates during the free dissolution, under quiescent and inductively stirred steel baths, were very similar. Under the experimental conditions used, the rate Controlling step of zirconium dissolution in liquid steel is reaction controlled.