| 对甲氧基苯乙烯在离子液体中的正离子聚合 |
| |
| 引用本文： | 宋雪超,伍一波,郭文莉,李树新.对甲氧基苯乙烯在离子液体中的正离子聚合[J].石油化工高等学校学报,2014(5):28-32,38. |
| |
| 作者姓名： | 宋雪超 伍一波 郭文莉 李树新 |
| |
| 作者单位： | 1. 北京化工大学材料科学与工程学院，北京 100029; 北京石油化工学院材料科学与工程学院，北京 102617
2. 北京石油化工学院材料科学与工程学院，北京 102617; 特种弹性体复合材料北京市重点实验室，北京 102617 |
| |
| 基金项目： | 国家自然科学基金，国家重点基础研究发展计划(2012CB626811)。 |
| |
| 摘 要： | 以咪唑磷酸盐类离子液体1-丁基-3-甲基咪唑六氟磷酸盐(bmim]PF6])作为溶剂,在-10℃下以2-氯-2,4,4-三甲基戊烷(TMPCl)、三氟化硼(BF3)为引发体系,实现了对甲氧基苯乙烯(p-MOS)的正离子聚合,得到的聚合物分子摩尔质量达到73 150g/mol,单体转化率超过93.4%。分析了反应温度对聚合的影响,聚合物分子摩尔质量以及聚合物末端结构等,提出了离子液体中对甲氧基苯乙烯正离子聚合的基元反应。并通过1 H-NMR对结构进行表征。研究证实bmim]PF6]离子液体中所得聚合物存在含氯末端基和双键末端两种末端结构。
|
| 关 键 词： | 咪唑磷酸盐类离子液体 对甲氧基苯乙烯 正离子聚合 绿色溶剂 |
The Cationic Polymerization of p-Methoxystyrene in Ionic Liquid |
| |
| Song Xuechao,Wu Yibo,Guo Wenli,Li Shuxin.The Cationic Polymerization of p-Methoxystyrene in Ionic Liquid[J].Journal of Petrochemical Universities,2014(5):28-32,38. |
| |
| Authors: | Song Xuechao Wu Yibo Guo Wenli Li Shuxin |
| |
| Affiliation: | Song Xuechao;Wu Yibo;Guo Wenli;Li Shuxin;College of Material Science and Engineering,Beijing University of Chemical Technology;Department of Material Science and Engineering,Beijing Institute of Petrochemical Technology;Special Elastic Composite Materials Key Laboratory of Beijing; |
| |
| Abstract: | Cationic polymerization of p-Methoxystyrene （p-MOS）was achieved in imidazole phosphate ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate （bmim ]PF6 ]） with 2-chloro-2,4,4-trimethyl pentane （TMPCl ） and boron trifluoride （BF3 ）as a initiating system at -10 ℃.The polymer molecular weight achieved 73 150 g/mol,and monomer conversion was more than 93.4%.The influence of reaction temperature and monomer concentrationon the polymerization was analyzed,and the molecular structure was characterized by 1 H-NMR.The results showed that there were two different ends structure of polymer,including chlorine end groups and double bond end groups,and the corresponding mechanism of cationic polymerization of p-Methoxystyrene in ionic liquid was proposed. |
| |
| Keywords: | Imidazole phosphate ionic liquid p-Methoxystyrene Cationic polymerization Green solvent |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
