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Effect of styrene–ethylene–butadiene–styrene and its synergetic effect with ethylene vinyl acetate on the mechanical,thermal, dielectric,and water‐treeing behaviors of crosslinked polyethylene
Authors:Zhisen Ma  Pingkai Jiang  Lichun Wang  Junsheng Yang
Affiliation:Shanghai Key Laboratory of Electrical Insulation and Thermal Aging, Department of Polymer Science and Engineering, Shanghai Jiaotong University, Shanghai 200240, People's Republic of China
Abstract:In this study, we investigated the effect of an aromatic polymer, styrene–ethylene–butadiene–styrene (SEBS), on the water‐tree resistance of crosslinked polyethylene (XLPE), and the synergetic effect of SEBS and ethylene vinyl acetate (EVA) was also investigated. The XLPE/SEBS and XLPE/SEBS/EVA samples were characterized by means of differential scanning calorimetry, scanning electron microscopy, mechanical measurements, and an accelerated water‐treeing experiment, and the obtained results clearly show the relevant influence of SEBS and EVA, and as expected, the addition of SEBS and EVA was found to synergistically influence the water‐tree resistance of XLPE more positively in comparison with that without the addition of EVA. In addition, it also indicated that the blends possessed excellent dielectric behaviors, such as the dielectric constant and dissipation factor. The crystallization of the blends decreased with increasing SEBS content and addition of EVA. However, the melting temperature of the blends increased with the addition of SEBS and EVA, but the melting temperature of the blends decreased with increasing SEBS content. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010
Keywords:blending  conjugated polymers  degradation  high performance polymers  polyethylene (PE)
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