| CO气相偶联合成草酸二甲酯Pd/α-Al2O3催化剂失活与再利用 |
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| 引用本文： | 穆仕芳,张鲁湘,宋军超,尚如静,张建利,崔发科,牛刚,魏灵朝.CO气相偶联合成草酸二甲酯Pd/α-Al2O3催化剂失活与再利用[J].工业催化,2019,27(1):1-5. |
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| 作者姓名： | 穆仕芳 张鲁湘 宋军超 尚如静 张建利 崔发科 牛刚 魏灵朝 |
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| 作者单位： | 1.河南理工大学安全科学与工程学院,河南 焦作 454000;2.河南能源化工集团研究总院有限公司,河南 郑州450046;3.宁夏大学省部共建煤炭高效利用与绿色化工国家重点实验室,宁夏 银川 750021;4.河南能源化工集团战略发展部,河南 郑州450046 |
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| 摘 要： | 作为合成气制乙二醇关键步骤之一,CO与亚硝酸甲酯合成草酸二甲酯备受关注。综述了近年来CO气相偶联合成草酸二甲酯Pd/α-Al2O3催化剂失活与再利用研究进展,探讨催化剂再利用工艺存在的问题,指出应根据在工业应用中出现的问题对Pd/α-Al2O3催化剂进行失活研究,在此基础上开发针对性的再生工艺;钯催化剂回收方面萃取法和吸附法逐渐成为研究重点,高效、低耗、短流程绿色工艺的开发是失活钯催化剂再利用的发展方向。
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| 关 键 词： | 催化剂工程 草酸二甲酯合成 Pd/α -Al2O3催化剂 失活原因 再生工艺 钯回收工艺 |
Deactivation and recovery of Pd/α-Al2O3 catalyst for gas-phase CO coupling to dimethyl oxalate |
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| Mu Shifang,Zhang Luxiang,Song Junchao,Shang Rujing,Zhang Jianli,Cui Fake,Niu Gang,Wei Lingchao.Deactivation and recovery of Pd/α-Al2O3 catalyst for gas-phase CO coupling to dimethyl oxalate[J].Industrial Catalysis,2019,27(1):1-5. |
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| Authors: | Mu Shifang Zhang Luxiang Song Junchao Shang Rujing Zhang Jianli Cui Fake Niu Gang Wei Lingchao |
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| Affiliation: | 1.School of safety science and engineering,Henan Polytechnic University,Jiaozuo 454000,Henan,China;2.Research Institute of Henan Energy and Chemical Industry Group Co.Ltd.,Zhengzhou 450046,Henan,China;3.State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering,Ningxia University,Yinchuan 750021,Ningxia,China;4.Strategic Development Department,Henan Energy and Chemical Industry Group Co.Ltd.,Zhengzhou 450046,Henan,China |
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| Abstract: | As one of the key steps in syngas to ethylene glycol,synthesis of dimethyloxalate(DMO) from CO and methyl nitrite has attracted much attention.Recent progress in deactivation and reuse of Pd/α-Al2O3catalyst for DMO synthesis was reviewed.Problems existing in the reutilization process of Pd/α-Al2O3 catalyst were analyzed,and future development direction was discussed.It was pointed out that research on deactivation of Pd/α-Al2O3 catalyst should based on problems in industrial application to develop target regeneration process.Extraction and adsorption process of Pd/α-Al2O3 catalyst recovery gradually became focus of this area.Development of high efficiency,low cost and green process was reutilization direction of deactivated Pd/α-Al2O3 catalyst. |
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| Keywords: | catalyst engineering dimethyl oxalate synthesis Pd/α-Al2O3 catalyst deactivation reason regeneration process Pd recovery |
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