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二氧化钛纳米结构形貌可控合成及光催化性能
引用本文:郭田辉,李欣竹,张守臣.二氧化钛纳米结构形貌可控合成及光催化性能[J].工业催化,2019,27(10):54-57.
作者姓名:郭田辉  李欣竹  张守臣
作者单位:大连理工大学化工与环境生命学部,辽宁 大连,116024;大连理工大学化工与环境生命学部,辽宁 大连,116024;大连理工大学化工与环境生命学部,辽宁 大连,116024
摘    要:以不同方法制备棒状、球状和花状3种形貌的TiO_2纳米粒子,采用X粉末衍射、扫描电子显微镜、荧光光谱和紫外-可见漫反射等对TiO_2纳米粒子进行结构及形貌分析。以亚甲基蓝为降解模型,分别在紫外光与可见光条件下对TiO_2纳米粒子进行光催化性能研究,分析TiO_2的形貌结构影响光催化性能的机理。结果表明,花状TiO_2纳米粒子光催化性能最好,其中高能晶面与微观形貌尺寸对TiO_2光催化性能具有重要影响。

关 键 词:催化化学  二氧化钛  光催化降解  高能晶面  形貌理论  ROS自由基

Morphology controllable synthesis and photocatalytic property of TiO2 nanostructures
Guo Tianhui,Li Xinzhu,Zhang Shouchen.Morphology controllable synthesis and photocatalytic property of TiO2 nanostructures[J].Industrial Catalysis,2019,27(10):54-57.
Authors:Guo Tianhui  Li Xinzhu  Zhang Shouchen
Affiliation:Faculty Chemical,Environmental and Biological Science and Technology,Dalian University of Technology,Dalian 116024,Liaoning,China
Abstract:Aseries of TiO2 with rod,spherical and flower morphologies weresynthesized successfully.The as-prepared catalysts were characterized by XRD、SEM、UV-VIS.Methylene blue(ME) was used as the aimed degradation material to observe the performance of photocatalysis under ultraviolet and visible light.The mechanism of the effect of morphology and structure of TiO2 on photocatalytic performance was analyzed.The results showed:photocatalytic effect of Flower-like(P25) was the best.The high energy facets and theoretic of morphology have an important influence on the photocatalytic of TiO2.
Keywords:catalytic chemistry  titanium dioxide  photocatalytic degradation  high energy facets  theoretic of themorphology  ROS radical  
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