溶液共混法制备聚氨酯/碳纳米管复合材料及其性能 |
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引用本文: | 王静荣,谢华清.溶液共混法制备聚氨酯/碳纳米管复合材料及其性能[J].玻璃钢/复合材料,2009,209(6):35-38. |
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作者姓名: | 王静荣 谢华清 |
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作者单位: | 上海第二工业大学城市建设与环境工程学院,上海,201209 |
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基金项目: | 上海高校选拔培养优秀青年教师科研专项基金,上海市重点学科建设项目 |
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摘 要: | 通过强酸处理方法对碳纳米管进行改性处理并对其结构和分散稳定性进行分析。采用溶液共混法制备了聚氨
酯/碳纳米管复合材料,利用FTIR对其结构进行了分析,探讨了碳纳米管对复合材料力学性能、热稳定性能以及弹
性回复率的影响。结果表明,碳纳米管经酸处理后添加了羧酸活性基团,提高了其在溶剂中的分散性|在复合材料
中,碳纳米管以较强氢键与大分子连接,复合材料的力学性能和热稳定性能都有所提高,而弹性回复率没有受到很
大影响。
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关 键 词: | 聚氨酯 碳纳米管 复合材料 溶液共混法 |
POLYURETHANE/CARBON NANOTUBE COMPOSITES PREPARED BY SOLUTION
MIXING AND THEIR PROPERTIES |
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Abstract: | Carbon nanotubes were treated with acid, and their structures and dispersion stability
were further investigated. Polyurethane/carbon nanotube composites were prepared by solution mixing
and their structures were characterized by FTIR. The mechanical properties, elastic recovery
behavior and thermal stabilization of the composites were analyzed. It indicated that the carboxylic
acid groups were added onto the carbon nanotubes and the dispersion stability of CNTs in DMAc was
improved. The CNTs were hydrogen bonded onto the polyurethane matrix. Consequently, the mechanical
and thermal properties of the composites were both enhanced, while the elastic recovery behavior
was little affected. |
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Keywords: | polyurethane carbon nanotubes composites solution mixing |
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