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Role of Amino Acids on <Emphasis Type="Italic">In Situ</Emphasis> Photografting of Jute Yarn with 3-(Trimethoxysilyl) Propylmethacrylate
Authors:M?Masudul?Hassan  M?Rabiul?Islam  Laurence?T?Drzal  Email author" target="_blank">Mubarak?A?KhanEmail author
Affiliation:(1) Department of Chemistry, M C College, 3100 Sylhet, Bangladesh;(2) Department of Chemistry, Jahangirnagar University, Dhaka, Savar, Bangladesh;(3) Composite Materials and Structures Center, Michigan State University, East Lansing, MI, USA;(4) Radiation and Polymer Chemistry Laboratory, Institute of Nuclear Science and Technology, Bangladesh Atomic Energy Commission, P.O. Box 3787, 1000 Dhaka, Bangladesh
Abstract:To improve the mechanical performance of natural lignocellulosic jute yarn, grafting with 3-(trimethoxysilyl) propylmethacrylate] (TMSPM) monomer has been performed on in situ UV radiation and optimized the monomer concentration (30%) and irradiation time (30 min). Effect of various amino acids (1%) as additives in TMSPM with photografted jute yarn at optimized system has been studied. The polymer loading (PL) and tensile properties like tensile strength (TS) and elongation at break (Eb) of treated samples were enhanced by incorporation of amino acids and the highest properties (TS = 300% and Eb = 386%) achieved by the sample treated with l-Arginine (Arg) with 32.5% PL value. Weak acid like 3% acetic acid and inorganic acid like 1% sulfuric acid were also incorporated in the optimized system of TMSPM grafting and compared their effect on the tensile properties with amino acid treated samples. Water absorption and weathering resistance of treated and untreated samples were also performed and treated sample showed lesser water uptake as well as less weight loss and mechanical properties as compared to untreated samples.
Keywords:Jute  photografting  UV radiation  natural fiber  biodegradable
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