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南欧大戟中一个新的假白榄烷型二萜
引用本文:宋智琴,穆淑珍,邸迎彤,郝小江.南欧大戟中一个新的假白榄烷型二萜[J].中国天然药物,2010(2):81-83.
作者姓名:宋智琴  穆淑珍  邸迎彤  郝小江
作者单位:中国科学院天然产物化学重点实验室;贵阳中医学院;中国科学院昆明植物研究所植物化学与西部植物资源国家重点实验室;
基金项目:supported by the Specialized Foundation for Talents of Guizhou Province(No.2008114); Specialized Foundation for Modernization of Traditional Chinese Medicine of Guizhou Province(No.20065041); the Ministry of Scienceand Technology(No.2007CB516813)~~
摘    要:目的:研究南欧大戟全草的化学成分。方法:采用硅胶柱色谱、凝胶柱色谱和MCI等分离纯化化合物,利用ESI-MS,IR,NMR确定化合物的结构。结果:分离鉴定了3个化合物,分别为:euphopeplin A(1),2α,5α,7β,8α,9α,14β-hexa-acetoxy-3β-benzoyloxy-15-hydroxyjatropha-6(17),11E-diene(2)和5α,8α,9β,10β,14α-pentaacetoxy-3β-benzoyloxy-15-hydroxy-pepluane(3)。结论:化合物1为一新化合物。

关 键 词:大戟科  大戟属  南欧大戟  二萜  假白榄烷型二萜

A New Jatrophane Diterpenoid from Euphorbia peplus
SONG Zhi-Qin ,MU Shu-Zhen ,DI Ying-Tong ,HAO Xiao-Jiang , The Key Laboratory of Chemistry for Natural Products of Guizhou Province , Chinese Academy of Sciences,Guiyang ,Guiyang College of Traditional Chinese Medicine,State Key Laboratory of Phytochemistry , Plant Resources in West China,Kunming Institute of Botany,Chinese Academy of Sciences,Kunming ,China.A New Jatrophane Diterpenoid from Euphorbia peplus[J].Chinese JOurnal of Natural Medicines,2010(2):81-83.
Authors:SONG Zhi-Qin    MU Shu-Zhen  DI Ying-Tong  HAO Xiao-Jiang  The Key Laboratory of Chemistry for Natural Products of Guizhou Province  Chinese Academy of Sciences  Guiyang  Guiyang College of Traditional Chinese Medicine  State Key Laboratory of Phytochemistry  Plant Resources in West China  Kunming Institute of Botany  Chinese Academy of Sciences  Kunming  China
Affiliation:SONG Zhi-Qin 1,2,MU Shu-Zhen 1,DI Ying-Tong 3,HAO Xiao-Jiang 1,3 1The Key Laboratory of Chemistry for Natural Products of Guizhou Province , Chinese Academy of Sciences,Guiyang 550002,2Guiyang College of Traditional Chinese Medicine,3State Key Laboratory of Phytochemistry , Plant Resources in West China,Kunming Institute of Botany,Chinese Academy of Sciences,Kunming 650204,China
Abstract:AIM:To study the chemical constituents of Euphorbia peplus.METHODS:Compounds 1-3 were isolated and purified by silica gel column chromatography,MCI and Sephadex LH-20.Their structures were mainly elucidated by spectroscopic analysis and physicochemical characteristics.RESULTS:Three compounds were identified as euphopeplin A(1),2α,5α,7β,8α,9α, 14β-hexaacetoxy-3β-benzoyloxy-15-hydroxyjatropha-6(17),11E-diene(2)and 5α,8α,9β,10β,14α-pentaacetoxy-3β-benzoy-loxy-15-hydroxypepluane(3).CONCLUSION:A new jatrophane diterpenoid,euphopeplin A(1)was isolated from Euphorbia peplus.
Keywords:Euphorbiaceae  Euphorbia  Euphorbia peplus  Diterpenoids  Jatrophane diterpenoids  
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