Transitions in Presence of Short Laser Pulses

Abstract

Accurate numerical calculations are carried out to investigate the validity of the two-state approximation in the case of resonant interactions between electromagnetic radiation and atoms. Short pulses are considered and the presence of the atomic spectrum is modelled by introducing a third, non-resonant, state. We show that the harmonics of the pulse profile may play a significant role in the dynamics of the process and may cause energy non-conserving transitions between the atomic states.