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碱性复合磺酸钙基脂的摩擦学性能及机理
引用本文:闻振中,夏延秋,刘志鲁.碱性复合磺酸钙基脂的摩擦学性能及机理[J].石油学报(石油加工),2013,29(1):151-156.
作者姓名:闻振中  夏延秋  刘志鲁
作者单位:1. 华北电力大学(北京) 能源动力与机械工程学院,北京 102206; 2. 中国科学院 兰州化学物理研究所,甘肃 兰州 730000
基金项目:中国科学院“百人计划”项目资助
摘    要:采用SRV摩擦磨损试验机评价了实验室制备的碱性复合磺酸钙基润滑脂在高、低温下的摩擦学性能,并采用三维轮廓扫描仪和X射线光电子能谱仪观察和分析了磨斑表面的磨损情况及表面元素的化学状态。结果表明,高温下碱性复合磺酸钙基润滑脂具有更好的减摩性能,但是其抗磨性能较之室温略有下降。产生这种情况的主要原因是高温下的摩擦表面比室温时有更高的化学反应活性,生成更多的硼酸钙和硫化亚铁,形成能抗磨减摩的覆盖膜。

关 键 词:碱性复合磺酸钙基润滑脂  摩擦磨损  X射线光电子能谱仪  摩擦机理  
收稿时间:2011-12-08

Tribological Behavior and Mechanism of Overbased Complex Calcium Sulfonate Grease
WEN Zhenzhong,XIA Yanqiu,LIU Zhilu.Tribological Behavior and Mechanism of Overbased Complex Calcium Sulfonate Grease[J].Acta Petrolei Sinica (Petroleum Processing Section),2013,29(1):151-156.
Authors:WEN Zhenzhong  XIA Yanqiu  LIU Zhilu
Affiliation:1. School of Energy Power and Mechanical Engineering, North China Electric Power University, Beijing 102206, China; 2. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
Abstract:The tribology properties of high and low temperature of the overbased complex calcium sulfonate grease made in laboratory were evaluated by using Optimol SRV reciprocating friction and wear tester. The worn volume and worn surface chemical composition of steel-steel contact were observed and analyzed by 3D figure scanner and X-ray photoelectron spectroscopy. The results showed that the overbased complex calcium sulfonate grease possessed better friction reducing properties at high temperature, but lower wear resistance than that at room temperature, for which the main reason was that the friction surface had higher chemical reactivity at high temperature than at room temperature, to generate more calcium borate and ferrous sulfide, forming a good film to reduce friction and worn volume of steel-steel contact.
Keywords:overbased calcium sulfonate complex grease  friction-wear  X-ray photoelectron spectroscopy  mechanism
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