| 阴离子导向组装：两个具有不同阳离子的多维Ag(I)配合物的晶体结构 |
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| 引用本文： | 王江云,顾文,王文珍,刘欣,廖代正.阴离子导向组装：两个具有不同阳离子的多维Ag(I)配合物的晶体结构[J].中国化学,2006,24(4):493-498. |
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| 作者姓名： | 王江云 顾文 王文珍 刘欣 廖代正 |
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| 作者单位： | Department of Chemistry, Nankai University, Tianjin 300071, China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China （No. 20371027） and Tianjin Science Foundation （No. 033609211）. |
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| 摘 要： | Assembly of Ag（CN）2]^- units with M（Ⅱ）-diamine complex cations Cu（LN-N）2]^2＋, where LN-N represents L2-diaminopropane （pn） and ethylenediamine （en）, afforded two complexes, Cu（pn）2]Ag2（CN）4] （1） and Cu（en）2]Ag3（CN）5] （2）, which were characterized by elemental analysis, IR, UV-Vis and ESR spectra. Single crystal X-ray analyses show that these complexes have 2D and 3D architectures through silver-silver interactions and other weak interactions. The luminescence behaviors of the two complexes were also studied by means of emission spectra.
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| 关 键 词： | 铜（Ⅱ）二胺配合物 银-银交互作用 发光行为 光谱分析 结构分析 |
| 收稿时间： | 2005-06-07 |
| 修稿时间： | 2005-06-072005-11-17 |
Cation Guided Assembly: Crystal Structures of Two Ag(I) Complexes in Versatile Dimensionalities with Different Counter Cations |
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| WANG Jiang-Yun, GU Wen, WANG Wen-Zhen, LIU Xin, LIAO Dai-Zheng.Cation Guided Assembly: Crystal Structures of Two Ag(I) Complexes in Versatile Dimensionalities with Different Counter Cations[J].Chinese Journal of Chemistry,2006,24(4):493-498. |
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| Authors: | WANG Jiang-Yun GU Wen WANG Wen-Zhen LIU Xin LIAO Dai-Zheng |
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| Affiliation: | Department of Chemistry, Nankai University, Tianjin 300071, China |
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| Abstract: | Assembly of Ag(CN)2]? units with M(II)‐diamine complex cations Cu(LN‐N)2]2+, where LN‐N represents 1,2‐diaminopropane (pn) and ethylenediamine (en), afforded two complexes, Cu(pn)2]Ag2(CN)4] ( 1 ) and Cu(en)2]Ag3(CN)5] ( 2 ), which were characterized by elemental analysis, IR, UV‐Vis and ESR spectra. Single crystal X‐ray analyses show that these complexes have 2D and 3D architectures through silver‐silver interactions and other weak interactions. The luminescence behaviors of the two complexes were also studied by means of emission spectra. |
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| Keywords: | Cu(II)‐diamine complex silver‐silver interaction luminescence behavior |
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